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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vermang, Bart
General Electric (Finland)
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (33/33 displayed)
- 2024Radiation versus environmental degradation in unencapsulated metal halide perovskite solar cellscitations
- 2024Toward Mass Production of Transition Metal Dichalcogenide Solar Cells: Scalable Growth of Photovoltaic-Grade Multilayer WSe2 by Tungsten Selenizationcitations
- 2024Rear Surface Passivation for Ink-Based, Submicron CuIn(S, Se)2 Solar Cellscitations
- 2024Liâ€Doping and Agâ€Alloying Interplay Shows the Pathway for Kesterite Solar Cells with Efficiency Over 14%citations
- 2024Toward Mass Production of Transition Metal Dichalcogenide Solar Cells: Scalable Growth of Photovoltaic-Grade Multilayer WSe2by Tungsten Selenization.citations
- 2024Li-doping and Ag-alloying interplay shows the pathway for kesterite solar cells with efficiency over 14%citations
- 2024Li-doping and Ag-alloying interplay shows the pathway for kesterite solar cells with efficiency over 14%citations
- 2023Ge-alloyed kesterite thin-film solar cells: previous investigations and current status – a comprehensive reviewcitations
- 2023Towards market commercialization: Lifecycle economic and environmental evaluation of scalable perovskite solar cellscitations
- 2023Facile Aqueous Solution-Gel route toward Thin Film CuBi2O4 Photocathodes for Solar Hydrogen Productioncitations
- 2023Ultrasonic spray coating of kesterite CZTS films from molecular inkscitations
- 2023Controlled li alloying by postsynthesis electrochemical treatment of Cu 2 ZnSn(S, Se) 4 absorbers for solar cellscitations
- 2022A study of quenching approaches to optimize ultrasonic spray coated perovskite layers scalable for PVcitations
- 2022Relevance of Ge incorporation to control the physical behaviour of point defects in kesteritecitations
- 2021Comparative study of Al2O3 and HfO2 for surface passivation of Cu(In,Ga)Se2 thin-films: An innovative Al2O3/HfO2 multi-stack designcitations
- 2021Comparative Study of Al2O3 and HfO2 for Surface Passivation of Cu(In,Ga)Se-2 Thin Films: An Innovative Al2O3/HfO2 Multistack Designcitations
- 2021A multi-stack Al2O3/HfO2 design with contact openings for front surface of Cu(In,Ga)Se-2 solar cellscitations
- 2021Revealing the electronic structure, heterojunction band offset and alignment of Cu2ZnGeSe4: a combined experimental and computational study towards photovoltaic applicationscitations
- 2020Investigating the electronic properties of Al2O3/Cu(In, Ga)Se-2 interfacecitations
- 2020Optical Lithography Patterning of SiO 2 Layers for Interface Passivation of Thin Film Solar Cellscitations
- 2020Growth of Sb2Se3 thin films by selenization of RF sputtered binary precursorscitations
- 2019A Study of the Degradation Mechanisms of Ultra Thin CIGS Solar Cells Submitted to a Damp Heat Environment
- 2019Crystallization properties of Cu2ZnGeSe4citations
- 2018Passivation of Interfaces in Thin Film Solar Cells: Understanding the Effects of a Nanostructured Rear Point Contact Layercitations
- 2018Optical Lithography Patterning of SiO<sub>2</sub> Layers for Interface Passivation of Thin Film Solar Cellscitations
- 2018Growth of Sb2Se3 thin films by selenization of RF sputtered binary precursors
- 2018Optical Lithography Patterning of SiO2 Layers for Interface Passivation of Thin Film Solar Cellscitations
- 2017Optimisation of rear reflectance in ultra-thin CIGS solar cells towards>20% efficiencycitations
- 2017Effect of the duration of a wet KCN etching step and post deposition annealing on the efficiency of Cu2ZnSnSe4 solar cellscitations
- 2016Progress in Cleaning and Wet Processing for Kesterite Thin Film Solar Cellscitations
- 2015Investigating the electronic properties of Al2O3/Cu(In, Ga)Se-2 interfacecitations
- 2014Potential-induced optimization of ultra-thin rear surface passivated CIGS solar cellscitations
- 2013Development of Rear Surface Passivated Cu(In,Ga)Se2 Thin Film Solar Cells with Nano-Sized Local Rear Point Contactscitations
Places of action
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article
Revealing the electronic structure, heterojunction band offset and alignment of Cu2ZnGeSe4: a combined experimental and computational study towards photovoltaic applications
Abstract
Cu2ZnGeSe4 (CZGSe) is a promising earth-abundant and non-toxic semiconductor material for large-scale thin-film solar cell applications. Herein, we have employed a joint computational and experimental approach to characterize and assess the structural, optoelectronic, and heterojunction band offset and alignment properties of CZGSe solar absorber. The CZGSe films were successfully prepared using DC-sputtering and e-beam evaporation systems and confirmed by XRD and Raman spectroscopy analyses. The CZGSe films exhibit a bandgap of 1.35 eV, as estimated from electrochemical cyclic voltammetry (CV) measurements and validated by first-principles density functional theory (DFT) calculations, which predicts a bandgap of 1.38 eV. A fabricated device based on the CZGSe as light absorber and CdS as a buffer layer yields power conversion efficiency (PCE) of 4.4% with VOC of 0.69 V, FF of 37.15, and JSC of 17.12 mA cm−2. Therefore, we suggest that interface and band offset engineering represent promising approaches to improve the performance of CZGSe devices by predicting a type-II staggered band alignment with a small conduction band offset of 0.18 eV at the CZGSe/CdS interface.