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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Villa, Alberto
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Metal-Free Catalytic Conversion of Veratryl and Benzyl Alcohols through Nitrogen-Enriched Carbon Nanotubescitations
- 2022Base‐free oxidative esterification of HMF over AuPd/nNiO‐TiO2 : When alloying effects and metal‐support interactions converge in producing effective and stable catalysts [Base-free Oxidative Esterification of HMF over AuPd/nNiO-TiO2. When Alloying Effects and Metal-support Interactions Converge in Producing Effective and Stable Catalysts]citations
- 2021Disclosing the role of gold on palladium - gold alloyed supported catalysts in formic acid decompositioncitations
- 2021Synthesis of palladium-rhodium bimetallic nanoparticles for formic acid dehydrogenationcitations
- 2020Capping agent effect on Pd-supported nanoparticles in the hydrogenation of furfuralcitations
- 2020DFT-assisted spectroscopic studies on the coordination of small ligands to palladium: from isolated ions to nanoparticlescitations
- 2019Promotion Mechanisms of Au Supported on TiO2 in Thermal- And Photocatalytic Glycerol Conversioncitations
- 2019Cyclic Voltammetry Characterization of Au, Pd, and AuPd Nanoparticles Supported on Different Carbon Nanofiberscitations
- 2019Hybrid Au/CuO Nanoparticles: Effect of Structural Features for Selective Benzyl Alcohol Oxidationcitations
- 2019Promotion Mechanisms of Au Supported on TiO 2 in Thermal- And Photocatalytic Glycerol Conversioncitations
- 2019AuPd-nNiO as an effective catalyst for the base-free oxidation of HMF under mild reaction conditionscitations
- 2019Voltammetric characterization of gold-based bimetallic (AuPt; AuPd; AuAg) nanoparticles
- 2019Promotion mechanisms of Au supported on TiO2 in thermal- and photocatalytic glycerol conversioncitations
- 2018Selective Oxidation of Veratryl Alcohol over Au-Pd/Ce0.62Zr0.38O2 Catalysts Synthesized by Sol-Immobilization: Effect of Au:Pd Molar Ratiocitations
- 2018Catalytic Performances of Au–Pt Nanoparticles on Phosphorous Functionalized Carbon Nanofibers towards HMF Oxidationcitations
- 2018Controlling the incorporation of phosphorus functionalities on carbon nanofibers: effects on the catalytic performance of fructose dehydrationcitations
- 2017Metal nanoclusters stabilized by pH-responsive microgels: Preparation and evaluation of their catalytic potentialcitations
- 2017Metal nanoclusters stabilized by pH-responsive microgels: Preparation and evaluation of their catalytic potentialcitations
- 2016Characterisation of gold catalystscitations
- 2010Pd on carbon nanotubes for liquid phase alcohol oxidationcitations
Places of action
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article
Controlling the incorporation of phosphorus functionalities on carbon nanofibers: effects on the catalytic performance of fructose dehydration
Abstract
Phosphorylated carbons have been reported to be effective catalysts in dehydration reactions for biomass valorization. The amount and the nature of P groups are a key parameter affecting the catalytic performances of functionalized materials. Herein, we investigate the role of structural and surface properties of carbon-based materials, specifically carbon nanofibers, in determining the amount of P-functionalities. In order to incorporate P groups on carbon surfaces, various carbon nanofibers (CNFs) with different graphitization degrees have been functionalized through treatment with a H3PO4-HNO3 mixture at 150 °C. The pristine materials, as well as the functionalization protocol, were properly selected to achieve an effective functionalization without drastically altering the morphology of the samples. Surface and structural properties of the synthesized functionalized materials have been investigated by means of transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. The catalytic behavior of phosphorylated carbon nanofibers has been evaluated in the selective dehydration of fructose to hydroxymethylfurfural (HMF) to elucidate structure-activity relationships.