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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Koplík, Jan
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Publications (6/6 displayed)
- 2023Influence of Anticorrosive Surface Treatment of Steel Reinforcement Fibers on the Properties of Ultra-High Performance Cement Compositecitations
- 2022Influence of Anticorrosive Surface Treatment of Steel Reinforcement Fibers on the Properties of Ultra-High Performance Cement Compositecitations
- 2022The thermal analysis of zinc oxide‑contaminated Portland cement blended with thiocyanates and determination of their effect on hydration and propertiescitations
- 2020The Characterization of Fixation of Ba, Pb, and Cu in Alkali-Activated Fly Ash/Blast Furnace Slag Matrixcitations
- 2020Influence of Pb Dosage on Immobilization Characteristics of Different Types of Alkali-Activated Mixtures and Mortarscitations
- 2018The ash from fluidized bed combustion as a donor of sulfates to the Portland clinkercitations
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article
The Characterization of Fixation of Ba, Pb, and Cu in Alkali-Activated Fly Ash/Blast Furnace Slag Matrix
Abstract
The fixation of heavy metals (Ba, Cu, Pb) in an alkali-activated matrix was investigated. The matrix consisted of fly ash and blast furnace slag (BFS). The mixture of NaOH and Na-silicate was used as alkaline activator. Three analytical techniques were used to describe the fixation of heavy metals—X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectroscopy (EDS), and X-ray powder diffraction (XRD). All heavy metals formed insoluble salts after alkaline activation. Ba was fixed as BaSO4, and only this product was crystalline. EDS mapping showed that Ba was cumulated in some regions and formed clusters. Pb was present in the form of Pb(OH)2 and was dispersed throughout the matrix on the edges of BFS grains. Cu was fixed as Cu(OH)2 and also was cumulated in some regions and formed clusters. Cu was present in two different chemical states; apart from Cu(OH)2, a Cu–O bond was also identified.