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Ghijsen, Jacques
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Publications (6/6 displayed)
- 2014The benefit of the European User Community from transnational access to national radiation facilitiescitations
- 2011Physical chemistry of the Mn/ZnO (0001̄) interface probed by hard X-ray photoelectron spectroscopycitations
- 2009Demixing processes in AgPd superlatticescitations
- 2004Structural and electronic properties of Ag-Pd superlatticescitations
- 2004Electronic Structure of Ag-Pd heterostructures
- 2003Interplay between morphology, structure, and electronic properties at diindenoperylene-gold interfacescitations
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article
Electronic Structure of Ag-Pd heterostructures
Abstract
The electronic structure of silver'palladium heterostructures is investigated, both experimentally and through ab-initio simulations. Synchrotron-induced photoelectron spectroscopy characterisations of the work function and the valence band structure are compared to and explained by simulations of slab and bulk heterostructures. Work functions and equilibrium geometries are shown to be in agreement with XPS, XRD, and STM measurements, and confirm in particular the pseudomorphic growth of Ag on Pd. Further insight into the differing behavior of the two terminating metal surfaces is extracted from the simulations.