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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Marins, Jessica Alves
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article
Hybrid polyaniline-coated sepiolite nanofibers for electrorheological fluid applications
Abstract
Hybrid materials constituted by sepiolite covered with polyaniline (PAni) with different compositions have been prepared using two simple methods: bulk and slurry oxidative polymerization. The hybrid nanofibers were characterized by Fourier transform-infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), thermo-gravimetric analysis (TGA), electrical conductivity, dielectric spectroscopy analysis and electrorheological response. Fiber-based nanocomposites with PAni nanoparticles well adhered to the sepiolite surface were successfully prepared by slurry polymerization. The best recovering of the nanofibers was observed in nanocomposites containing 46 wt% of PAni, (SP 50:50s sample) as indicated by FTIR and TEM and quantified by TGA analysis. Also the best electrorheological response was obtained with the corresponding suspensions containing 10 wt% of the hybrid material suspended in castor oil. The values of the field induced shear modulus in the linear viscoelastic region : G' = 536 kPa at E=2 kV/mm is higher than those found for the suspensions of pure components, PAni or sepiolite, and one of the best values obtained with conventional ER fluids. A model to estimate the interaction between two nanofibers has been proposed considering the length and thickness of the nanofiber, calculated by TEM.