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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Faure-Vincent, Jérôme
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2022D-π-A-Type Pyrazolo[1,5-a]pyrimidine-Based Hole-Transporting Materials for Perovskite Solar Cells: Effect of the Functionalization Positioncitations
- 2020Water content control during solution-based polymerization: a key to reach extremely high conductivity in PEDOT thin filmscitations
- 2018Triphenylamine 3,6-carbazole derivative as hole-transporting material for mixed cation perovskite solar cells
- 2018Triphenylamine 3,6-carbazole derivative as hole-transporting material for mixed cation perovskite solar cells
- 2018Carbazole-based twin molecules as hole-transporting materials in dye-sensitized solar cellscitations
- 2017Insulated molecular wires: sheathing semiconducting polymers with organic nanotubes through heterogeneous nucleationcitations
- 2015Enhanced Charge Separation in Ternary P3HT/PCBM/CuInS 2 Nanocrystals Hybrid Solar Cellscitations
- 2015Metallic behaviour of acid doped highly conductive polymerscitations
- 2014Synthesis, optoelectronic and photovoltaic properties of conjugated alternating copolymers incorporating 2,1,3-benzothiadiazole or fluorenone units: a comparative studycitations
- 2014Charge carrier transport and low electrical percolation threshold in multiwalled carbon nanotube polymer nanocompositescitations
- 2013Colloidal CuInSe2 nanocrystals thin films of low surface roughnesscitations
- 2013Low electrical percolation threshold in multiwalled carbon nanotube polymer nanocomposites and charge carrier transport
- 2013SnS thin films realized from colloidal nanocrystal inkscitations
- 2012Comparison of simulations to experiment for a detailed analysis of space-charge-limited transient current measurements in organic semiconductorscitations
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article
Triphenylamine 3,6-carbazole derivative as hole-transporting material for mixed cation perovskite solar cells
Abstract
A new hole transporting material based on 3,6-disubstituted carbazole (3,6Cz-TPA) was synthesized through a one-step approach and was used as hole-transporting material in perovskite solar cells. The HTM exhibits molecular glass behavior and a high glass transition temperature of 146 °C. A hole-mobility of 7.0 × 10−6 cm2 V−1 s−1 has been measured which is slightly lower than the mobility of spiro-OMeTAD (2.5 × 10−5 cm2 V−1 s−1). The HOMO energy level, similar to the HOMO of spiro-OMeTAD, is suitable to allow the hole injection from the perovskite. Solar cells based on organic–inorganic hybrid cation perovskite light absorber have been built. The optimization of the concentration of the HTM shows an optimal concentration around 30 mM. Finally, the perovskite cells based on 3,6Cz-TPA as HTM lead to a power conversion efficiency around 16%, similar to the most commonly used spiro-OMeTAD (17%).