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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Osman, Ahmed I.
Queen's University Belfast
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Starch-grafted polyacrylic acid copolymer with acrylamide: an advanced adsorbent for Victoria green B dye removal and environmental remediationcitations
- 2024Advanced methods for treating gemfibrozil and carbamazepine in wastewater: a reviewcitations
- 2024Advancements in battery materials: bio-based and mineral fillers for next-generation solid polymer electrolytescitations
- 2024Membrane Technology for Energy Saving: Principles, Techniques, Applications, Challenges, and Prospectscitations
- 2024Enhancing the biodegradability, water solubility, and thermal properties of polyvinyl alcohol through natural polymer blending: an approach toward sustainable polymer applicationscitations
- 2024Innovations in hydrogen storage materials: synthesis, applications, and prospectscitations
- 2024Fluoride removal using nanofiltration-ranged polyamide thin-film nanocomposite membrane incorporated titanium oxide nanosheetscitations
- 2024Novel nanocomposite of carbonized chitosan-zinc oxide-magnetite for adsorption of toxic elements from aqueous solutionscitations
- 2024Nanostructured Mn@NiO composite for addressing multi-pollutant challenges in petroleum-contaminated watercitations
- 2024Synthesis of highly basic, low-cost iron oxides from tin can waste as valorization of municipal solid waste and study of their catalytic efficiency as potent catalysts for MEK productioncitations
- 2024Green synthesis of Mn 3 O 4 @CoO nanocomposites using Rosmarinus officinalis L. extract for enhanced photocatalytic hydrogen production and CO 2 conversioncitations
- 2023Optimizing barium promoter for nickel catalyst supported on yttria-stabilized zirconia in dry reforming of methane
- 2023Natural nutraceuticals for enhancing yogurt properties: a reviewcitations
- 2023Biofuel production, hydrogen production and water remediation by photocatalysis, biocatalysis and electrocatalysiscitations
- 2023Biofuel production, hydrogen production and water remediation by photocatalysis, biocatalysis and electrocatalysiscitations
- 2023Direct and easily prepared nanocomposite impurity-free hydroxyapatite derived from CKD as an effective catalyst for trans-2-butene productioncitations
- 2022Engineered magnetic oxides nanoparticles as efficient sorbents for wastewater remediation: a reviewcitations
- 2022Highly basic and active ZnO–x% K 2 O nanocomposite catalysts for the production of methyl ethyl ketone biofuelcitations
- 2022Mg–O–F nanocomposite catalysts defend against global warming via the efficient, dynamic, and rapid capture of CO 2 at different temperatures under ambient pressurecitations
- 2021Engineered magnetic oxides nanoparticles as efficient sorbents for wastewater remediation: a reviewcitations
- 2021MoS 2 -based nanocomposites:synthesis, structure, and applications in water remediation and energy storage: a reviewcitations
- 2021Circular economy approach of enhanced bifunctional catalytic system of CaO/CeO2 for biodiesel production from waste loquat seed oil with life cycle assessment study
- 2020Renewable cellulosic nanocomposites for food packaging to avoid fossil fuel plastic pollution: a reviewcitations
Places of action
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article
Circular economy approach of enhanced bifunctional catalytic system of CaO/CeO2 for biodiesel production from waste loquat seed oil with life cycle assessment study
Abstract
Herein, we utilised Loquat seed oil as a waste resource to produce biodiesel over a novel bifunctional catalyst system based on CaO loaded on a ceria oxide support. The catalysts were characterised using XRD, SEM-EDX, SBET STEM, and TPD analyses, followed byparametric analysis tooptimise thecatalyst performance. The XPS analysis showed a strong synergistic effect between CaO and CeO2 support. The parametric study revealed that the most active catalyst (15 wt% CaO-CeO2) showed optimum biodiesel yield was 90.14 (±0.1) wt% at a temperature of 70 ◦C, methanol: oil of 9, time of 90 min and 4 wt% of catalyst. The reusability test showed that when the most active catalyst was calcined and reused, the biodiesel yield was almost the same ±0.5%; however, when biodiesel production was used without calcination, the biodiesel yield was reduced by 15%. The quality of the produced biodiesel was investigated by the American Society for Testing and Materials (ASTM) and European Union (EU) Standards. It showed that it satisfied all standards and could be used as potential alternative fuel instead of fossil diesel from novel Loquat seed oil. The Life cycle Assessment (LCA) was condcuted to assess environmental feasibility of the process with 1000 kg of biodiesel as 1 functional unit (FU). The LCA using midpoint indicators (from CML-IA baseline V3.06 method) showed the cumulative abiotic depletion of fossil resources over the entire process of biodiesel production was 26349 MJ, global warming potential was 1129 kg CO2 eq, and human health toxicity was 422 kg 1,4-DB eq (kg 1,4 dichlorobenzene equivalent) per FU. The highest damage in most environmental categories was observed during catalyst preparation and regeneration. This was confirmed in endpoint LCA findings (ReCiPe 2016 Endpoint (E) V1.04), where catalyst preparation contributed to human health (119.2 Point (Pt)), ecosystems damage (9.3 Pt) and resources depletion (0.5 Pt). Furthermore, the net energy ratio was 2.23 for the biodiesel production process (computed as output energy/ input energy) by considering allocation of output energy due to biodiesel and glycerol.