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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Betelu, Stéphanie
Bureau de Recherches Géologiques et Minières
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (28/28 displayed)
- 2024Optimization of experimental conditions of PFOA defluorination using DMSO/NaOH mixture
- 2024Over a year follow-up of parameters of a cemento-bentonitic filling material (CBFM) and of the corrosion potential of a carbon steel lining submerged by the CBFM, in an underground gallery cell
- 2024Long term monitoring of physical and chemical parameters of a cemento-bentonitic filling material (CBFM) and of corrosion potential ofa horizontal pipe made of carbon steel, submerged by the CBFM intoa sealed cell of underground gallery
- 2024Influence of microstructure and pore saturation in measuring corrosion rates of a carbon steel API 5L X65 in contact with cement grout in future nuclear waste disposal program
- 2023Numerical Insights into the Ability of Indirect Galvanostatic Pulse in Wenner Configuration to Locate Corroding Areas in Macrocell Corrosion of Steel in Concrete
- 2023Corrosion and inhibition of carbon steel XC38 in a standardized reconstituted geothermal water (SRGW) at 100°C and 120 bars of pressure in the absence or presence of biosourced inhibitors
- 2023Inversion of non-invasive resistivity measurements in fourelectrodes configuration for corrosion characterization in reinforced concrete samples
- 2023Corrosion control of ruthenium oxy-hydroxide coating for the development of robust pH sensors: observation and monitoring of the near field of a nuclear waste disposal site
- 2023Influence of polysulfide radicals on the mechanisms and intensity of corrosion of a carbon steel API 5L X65 in contact with cement grout in future nuclear waste disposal program ; Influence des radicaux de polysulfures sur les mécanismes et l'intensité de la corrosion d'un acier au carbone API 5L X65 en contact avec un coulis de ciment dans un futur programme de stockage de déchets nucléaires
- 2023Corrosion Current Density of API 5L X65 Carbon Steel in Contact with Natural Callovian-Oxfordian Clay Pore Water, Assessed by Various Electrochemical Methods over 180 Dayscitations
- 2023Influence of polysulfide radicals on the mechanisms and intensity of corrosion of a carbon steel API 5L X65 in contact with cement grout in future nuclear waste disposal program
- 2022Comparative study of the effectiveness of organic petro-or biosourced surfactants in inhibiting carbon steel corrosion in a standardized reconstituted geothermal water (RGW)
- 2022Assessement of electrochemical behaviour and of corrosion current density of the carbon steel API 5L X65 in contact with cement grout in a nuclear waste disposal program
- 2022Corrosion current density evolution of the carbon steel API 5L X65 in contact with natural callovo-oxfordian water assessed by various electrochemical methods
- 2022Corrosion current density evolution of the carbon steel API 5L X65 in contact with natural callovo-oxfordian water assessed by various electrochemical methods
- 2022Assessement of electrochemical behaviour and of corrosion current density of the carbon steel API 5L X65 in contact with cement grout in a nuclear waste disposal program
- 2022Comparative study of the effectiveness of organic petro-or biosourced surfactants in inhibiting carbon steel corrosion in a standardized reconstituted geothermal water (RGW)
- 2022Mechanism and kinetics of reductive dechlorination of hexachlorobutadiene and hexachloroethane by bimetallic Pd/Fe microparticles using an indirect and continuous monitoring of iron corrosion
- 2022CORROSION DENSITY OF THE CARBON STEEL API 5L X65 IN CONTACT WITH CALLOVO-OXFORDIAN CLAY PORE WATER ASSESSED BY USING VARIOUS ELECTROCHEMICAL METHODS
- 2022CORROSION DENSITY OF THE CARBON STEEL API 5L X65 IN CONTACT WITH CALLOVO-OXFORDIAN CLAY PORE WATER ASSESSED BY USING VARIOUS ELECTROCHEMICAL METHODS
- 2022Mechanisms and kinetics of carbon steel corrosion/scaling and inhibition in actual or reconstituted and treated geothermal waters
- 2021Mechanisms and kinetics of carbon steel corrosion/scaling and inhibition in actual or reconstituted and treated geothermal waters
- 2018Exploration into the ionic exchanges in the Ni/Fe Lamellar Double Hydroxide by in-situ techniques under polarization
- 2017Intercomparison of Ta and Ti solid-electrodes for pH measurements under oxic and anoxic conditions in reconstituted waters of a future nuclear waste disposal
- 2013Improved monitoring of the reductive dechlorination of PCE in polluted soils by using geophysical and electrochemical measurements carried out in columns
- 2012Mechanistic and kinetic study of pyrite (FeS2)-hydrogen (H2) interaction at 25°C using electrochemical techniques
- 2012Mechanistic study of pyrite reduction by hydrogen in NaCl 0.1 M at 90°C using electrochemical techniques
- 2012H-terminated polycrystalline boron doped diamond electrode for geochemical sensing into underground components of nuclear repositories
Places of action
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document
Intercomparison of Ta and Ti solid-electrodes for pH measurements under oxic and anoxic conditions in reconstituted waters of a future nuclear waste disposal
Abstract
International audience ; In France, the deep geological disposal has been chosen to manage long-lived high and middle activity nuclear waste. This project is supervised by " the Agence National pour la Gestion des Déchets Radioactif" (ANDRA-French national radioactive waste management agency). An underground research laboratory (URL), dedicated to host-rock properties characterization was built at approximately-490m depth in the Callovo-Oxfordian geological formation (COx), which is a potential candidate for nuclear waste disposal. Based on this overall strategy, Andra has analysed the technical requirements that must be met by adapted monitoring equipment. First, these must be able to provide information on key THMCR (Thermal-Hydraulic-Mechanical-Chemical and Radiological) processes, to provide a three-dimensional image of its behaviour and thus to understand the underground installation functioning, in particular the cell interactions with the near-field. This study aims to develop innovative all-solid-state electrodes made of iridium (Ir), ruthenium (Ru), tantalum (Ta), titanium (Ti), tungsten (W), niobium (Nb) and a tin-lead alloy (Sn/Pb), for pH measurement. Moreover, the potentiometric response of these electrodes is mainly based on Metal Oxide (M x O y)/Metal (M) equilibriums, which make them react to changes of oxygen partial pressures. For now, the antimony electrode (Sb) showed excellent results regarding the measure of pH under oxic and anoxic conditions. Nevertheless, it is necessary to multiply the electrode materials considered for pH measurements, for preventing a dysfunction of electrodes which could occur over time. By multiplying the electrode materials for pH measurement, we indirectly increase, firstly, the measurement reliability by giving the possibility to inter-compare the potentiometric responses of the set of the electrodes dedicated to pH, and secondly, the monitoring duration, in the case of electrode surface alterations, which could be caused by variations of the physical and ...