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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Brosse, Nicolas
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Isolation and Structural Characterization of Natural Deep Eutectic Solvent Lignin from Brewer’s Spent Grainscitations
- 2024A comprehensive review on processing, characteristics, and applications of cellulose nanofibrils/graphene hybrid-based nanocomposites: Toward a synergy between two-star nanomaterialscitations
- 2024Preparation and Characterization of Lignin Nanoparticles from Different Plant Sourcescitations
- 2023Investigation of the performance of needle-punched nonwoven fabrics using Triumfetta cordifolia and thermoplastic fibers, compared to other commercial bast fibers used in preformed biosourced compositescitations
- 2023Development of chitosan green composites reinforced with hemp fibers : study of mechanical and barrier properties for packaging applicationcitations
- 2022Preparation and characterization of formaldehyde-free wood adhesive from mangrove bark tannincitations
- 2022Preparation and characterization of formaldehyde-free wood adhesive from mangrove bark tannincitations
- 2021Extraction of acetylated glucuronoxylans and glucomannans from Okoume (Aucoumea klaineana Pierre) sapwood and heartwood by steam explosioncitations
- 2021Extraction of acetylated glucuronoxylans and glucomannans from Okoume (Aucoumea klaineana Pierre) sapwood and heartwood by steam explosioncitations
- 2018Production of oil palm (Elaeis guineensis) fronds lignin-derived non-toxic aldehyde for eco-friendly wood adhesivecitations
- 2018Production of oil palm (Elaeis guineensis) fronds lignin-derived non-toxic aldehyde for eco-friendly wood adhesivecitations
- 2017A Multitechnique Characterization of Lignin Softening and Pyrolysiscitations
- 2015Antioxidant and anticorrosive properties of oil palm frond lignins extracted with different techniquescitations
- 2015Preparation and Characterization of Lignin Polyols from the Residues of Oil Palm Empty Fruit Bunchcitations
- 2015Preparation and Characterization of Lignin Polyols from the Residues of Oil Palm Empty Fruit Bunch
- 2013Investigation of the Effects of Ionic Liquid 1-Butyl-3-methylimidazolium Acetate Pretreatment and Enzymatic Hydrolysis of Typha capensiscitations
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article
Preparation and Characterization of Lignin Polyols from the Residues of Oil Palm Empty Fruit Bunch
Abstract
In this work, lignin polyols were prepared from the liquefaction of kraft lignin and from the direct liquefaction of Elaeis guineensis lignocellulosic waste. The liquefaction reaction was performed with polyhydric alcohols using sulfuric acid as catalyst at 160 °C. The physical and chemical characterizations of lignin and lignin polyols were conducted by elemental analysis, Fourier transform-infrared spectroscopy, 1 H and 13 C nuclear magnetic resonance (NMR) spectroscopy, molecular weight distribution, and thermogravimetric analysis (TGA). Quantitative 13 C NMR showed that all aliphatic hydroxyl group values of polyols noticeably increased with the use of the two methods compared to kraft lignin. The average molecular weight analysis of the liquefied product showed that it exhibited high molecular weight compared to kraft lignin. Both structural and thermal characteristics suggest that lignin polyols would be a good substitute for kraft lignin in the synthesis of polymeric compounds such as environmentally friendly resins or wood adhesives, as it presents higher amounts of activated free ring positions, higher molecular weight, and high thermal stability.