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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tripkovic, Vladimir
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2018Comparative DFT+U and HSE Study of the Oxygen Evolution Electrocatalysis on Perovskite Oxidescitations
- 2016Exploring the Lanthanide Contraction to Tune the Activity and Stability of Pt
- 2016Exploring the Lanthanide Contraction to Tune the Activity and Stability of Pt
- 2015Controlling the Activity and Stability of Pt-Based Electrocatalysts By Means of the Lanthanide Contraction
- 2015Comparison between the Oxygen Reduction Reaction Activity of Pd<sub>5</sub>Ce and Pt<sub>5</sub>Ce: The Importance of Crystal Structurecitations
- 2014Formic Acid Oxidation at Platinum-Bismuth Clusterscitations
- 2014Insight into the Effect of Sn on CO and Formic Acid Oxidation at PtSn Catalystscitations
- 2014Intermetallic Alloys as CO Electroreduction Catalysts-Role of Isolated Active Sitescitations
- 2014Engineering the Activity and Stability of Pt-Alloy Cathode Fuel-Cell Electrocatalysts by Tuning the Pt-Pt Distance
- 2013First Principles Investigation of Zinc-anode Dissolution in Zinc-air Batteriescitations
Places of action
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document
Exploring the Lanthanide Contraction to Tune the Activity and Stability of Pt
Abstract
The high platinum loadings required to compensate for the slow kinetics of the oxygen reduction reaction (ORR) impede the widespread uptake of polymer electrolyte membrane fuel cells. In order to improve the ORR kinetics and reduce the Pt loading, we can tailor the electronic properties of the Pt surface atoms by means of alloying Pt with other metals. Researchers have intensively studied alloys of Pt with late transition metals such as Ni and Co during the last decades. However, these compounds typically degrade under fuel cell reaction conditions, due to dealloying. In contrast, alloys of Pt and lanthanides present very negative enthalpy of formation [1,2], which should increase their resistance to degradation.