| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Stephens, Ifan Erfyl Lester
Imperial College London
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2018Scalable Synthesis of Carbon-Supported Platinum–Lanthanide and −Rare-Earth Alloys for Oxygen Reductioncitations
- 2017New Platinum Alloy Catalysts for Oxygen Electroreduction Based on Alkaline Earth Metalscitations
- 2016Exploring the Lanthanide Contraction to Tune the Activity and Stability of Pt
- 2015Synchrotron Based Structural Investigations of Mass-Selected PtxGd Nanoparticles and a Gd/Pt(111) Single Crystal for Electrochemical Oxygen Reduction
- 2015Controlling the Activity and Stability of Pt-Based Electrocatalysts By Means of the Lanthanide Contraction
- 2015What Is the Optimum Strain for Pt Alloys for Oxygen Electroreduction?
- 2014Oxygen Evolution on Model Well-Characterised Mass-Selected Nanoparticles of RuOx
- 2014Understanding the Oxygen Reduction Reaction on a Y/Pt(111) Single Crystal
- 2014Iron-Treated NiO as a Highly Transparent p-Type Protection Layer for Efficient Si-Based Photoanodescitations
- 2011Tuning the Activity of Pt(111) for Oxygen Electroreduction by Subsurface Alloyingcitations
Places of action
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document
Exploring the Lanthanide Contraction to Tune the Activity and Stability of Pt
Abstract
The high platinum loadings required to compensate for the slow kinetics of the oxygen reduction reaction (ORR) impede the widespread uptake of polymer electrolyte membrane fuel cells. In order to improve the ORR kinetics and reduce the Pt loading, we can tailor the electronic properties of the Pt surface atoms by means of alloying Pt with other metals. Researchers have intensively studied alloys of Pt with late transition metals such as Ni and Co during the last decades. However, these compounds typically degrade under fuel cell reaction conditions, due to dealloying. In contrast, alloys of Pt and lanthanides present very negative enthalpy of formation [1,2], which should increase their resistance to degradation.