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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gossé, S.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2018High temperature corrosion phenomena during a nuclear severe accident - The corium-concrete interaction
- 2018Thermodynamic Assessment of the Fe-Te System. Part I: Experimental studycitations
- 2017Thermodynamic investigation of the Cr-O-U and Cr-O-Zr systems
- 2017Thermodynamic modelling of key metallic sub-systems for the treatment of mid-level wastes
- 2017Thermodynamic modelling of key metallic sub-systems for the treatment of mid-level wastes
- 2017The TAF-ID database Application calculations to severe accidents and irradiated fuel
- 2016Experimental and thermodynamic calculations results on pwr and srf corium subsystems
- 2016Thermodynamic assessment of the PdRhRu system using calphad and first-principles methodscitations
- 2016High temperature experimental contribution to the thermodynamic modeling of corium pools
- 2016High temperature experimental contribution to the thermodynamic modeling of corium pools
- 2015Experimental investigation and thermodynamic modelling of the in-vessel corium for severe accident studies in PWR reactors
- 2015Experimental investigation and thermodynamic modelling of the in-vessel corium for severe accident studies in PWR reactors
- 2015Experimental study and thermodynamic modelling of corium mixtures Application to severe accidents in Pressurized Water Reactors
- 2015Modélisation thermodynamique de l'interaction entre le verre et les phases molybdates.
- 2012Mechanism of RuO2 Crystallization in Borosilicate Glass: An Original in Situ ESEM Approachcitations
- 2011Thermodynamic study of the uranium–vanadium systemcitations
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document
Thermodynamic modelling of key metallic sub-systems for the treatment of mid-level wastes
Abstract
The metallic waste resulting from the synthesis of mixed (U,Pu)O$_2$ oxides fuel is characterised by a mid-level contamination and needs to be treated before disposal. A possible process designed for this problem consists in melting such metals and then mixing them together with a SiO$_2$-Na$_2$O silicate melt in order to accommodate actinides into a stable glass matrix.Because of the large number of alloying elements involved in this process, the Calphad method is used to predict the thermodynamic behaviour of the metallic phase and the reactions between the metallic and oxide liquids at high temperature. This work focuses on the thermodynamic modelling of several metallic sub-systems of interest that may form during the processing of waste.A particular attention will be paid to the main elements present in the metallic waste Al-Cu-Fe-Si-U. Differential Thermal Analysis coupled with Electron Microscopy are used to better document a variety of binary and ternary sub-systems. These new data are also used to validate the database under development, which eventually will be representative of the entire metallic melt.