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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vitrac, Olivier
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Development of extrusion blown films of poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate) blends for flexible packagingcitations
- 2019DEVELOPMENT OF BIODEGRADABLE POLY(HYDROXYBUTYRATE-CO-HYDROXYVALERATE) AND POLY(BUTYLENE SUCCINATE-CO-ADIPATE) BLENDS: TOUGHENING EFFECT
- 2017Off-lattice Flory-Huggins approximations for the tailored calculation of activity coefficients of organic solutes in random and block copolymerscitations
- 2014Sorption of n-hexane in amorphous polystyrenecitations
- 2011Controlling the molecular interactions to improve the diffusion barrier of biosourced polymers to organic solutescitations
- 2010A tailored approach to optimize the barrier properties of Poly(lactic acid) nanocomposites for food contact purposes
- 2010Molecular dynamics simulations of the chain dynamics in monodisperse oligomer melts and of the oligomer tracer diffusion in an entangled polymer matrixcitations
- 2008Accuracy and reliability of different models used for the prediction of the migration from monolayer and multilayer materials
- 2005Functional barriers: Properties and evaluationcitations
Places of action
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conferencepaper
A tailored approach to optimize the barrier properties of Poly(lactic acid) nanocomposites for food contact purposes
Abstract
A new kind of barrier materials, so called “chaotic” materials and involving interactions with nano-charges, is presented. By contrast with conventional use of nano-clays, the sought effect consists not in increasing the tortuosity to penetrants but in increasing the dwelling times of solutes around accessible clays designed on purpose. The paper reviews several theoretical models that explain why effective diffusion coefficients (D) decay due to entropic trapping. The physical concepts are applied to a simple material made of a deactivated glass column filled with montmorillonites and exposed to several gas phases enriched in organic solutes. In this simple physical model, a carrier gas replaces the polymer so that molecular effects can be visualized and analyzed almost in real time with a simple flame-ionization detector. The future directions to combine a bio-sourced material (PLA) and montmorillonites are outlined.