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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Perrin, Jean-Christophe
Université de Lorraine
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (3/3 displayed)
- 2019CONJOINT EFFECTS OF CHEMICAL AND MECHANICAL DEGRADATION STRESSORS ON FUEL CELL PFSA MEMBRANES
- 2018Characterization of Nafion ®XL properties after ex-situ and in-situ degradations
- 2014A review of PEM fuel cell durability: materials degradation, local heterogeneities of aging and possible mitigation strategiescitations
Places of action
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conferencepaper
CONJOINT EFFECTS OF CHEMICAL AND MECHANICAL DEGRADATION STRESSORS ON FUEL CELL PFSA MEMBRANES
Abstract
To improve the lifetime of proton-exchange membrane (PEM) fuel cells, it is necessary to get a better understanding of the degradation mechanisms of their perfluorosulfonic acid (PFSA) electrolyte. In this work, an investigation on the effects of radical attacks (i.e. Fenton's reagents exposure) was carried out. The results confirmed that the chemical degradation of PFSA depends significantly on hydrogen peroxide (H2O2) and iron (Fe 2+) concentration and made it possible to optimize the degradation rate. Secondly, a specific custom-made device was developed to examine the impact of coupled chemical and mechanical degradations. The results showed that a cyclic mechanical stress leads to an accelerated chemical decomposition.