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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tonelli, Domenica
University of Bologna
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2022Nanoparticles of Mixed-Valence Oxides MnXCO3-XO4 (0 ≤ X ≤ 1) Obtained with Agar-Agar from Red Algae (Rhodophyta) for Oxygen Evolution Reactioncitations
- 2020Different Electrochemical Sensor Designs Based on Diazonium Salts and Gold Nanoparticles for Pico Molar Detection of Metalscitations
- 2020Needle-type organic electrochemical transistor for spatially resolved detection of dopamine
- 2016Electrocatalytic determination of thiols using hybrid Copper Cobalt Hexacyanoferrate modified glassy carbon electrodecitations
- 2012An insight into the electrochemical behavior of Co/Al Layered Double Hydroxide thin films prepared by electrodeposition
- 2012Synthesis Route to Supported Gold Nanoparticle Layered Double Hydroxides as Efficient Catalysts in the Electrooxidation of Methanol.
- 2009Visualization of electrocatalytic activity of microstructured metal hexacyanoferrates by means of redox competition mode of scanning electrochemical microscopy (RC-SECM)
Places of action
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article
Synthesis Route to Supported Gold Nanoparticle Layered Double Hydroxides as Efficient Catalysts in the Electrooxidation of Methanol.
Abstract
This work describes a new one-step method for the preparation of AuNP/LDH nanocomposites via the polyol route. The novelty of this facile, simple synthesis is the absence of additional reactants such as reductive agents or stabilizer, which gives the possibility to obtain phase-pure systems free of undesiderable effect. The AuNP formation is confirmed by SEM,TEM, PXRD, and XAS; moreover, the electrochemical characterization is also reported. The electrocatalytic behavior of AuNP/LDH nanocomposites has been investigated with respect to the oxidation of methanol in basic media and compared with that of pristine NiAl-Ac. The 4-fold highest catalytic efficiency observed with AuNP/LDH nanocomposites suggests the presence of a synergic effect between Ni and AuNP sites. The combination of these experimental findings with the low-cost synthesis procedure paves the way for the exploitation of the presented nanocomposites materials as catalysts for methanol fuel cells.