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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Daturi, Marco
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Hydroxyapatite: A Matrix for Metal Exsolution Leading to Highly Dispersed Catalytically Active Speciescitations
- 2023Upgrading the PtCu intermetallic compounds: The role of Pt and Cu in the alloycitations
- 2016Metal Organic Framework Crystals in Mixed-Matrix Membranes: Impact of the Filler Morphology on the Gas Separation Performancecitations
- 2013Isomorphous Substitution in a Flexible Metal–Organic Framework: Mixed-Metal, Mixed-Valent MIL-53 Type Materialscitations
- 2013Nitric Oxide Adsorption and Delivery in Flexible MIL-88(Fe) Metal-Organic Frameworks
- 2011A co-templating route to the synthesis of Cu SAPO STA-7, giving an active catalyst for the selective catalytic reduction of NO
- 2011A co-templating route to the synthesis of Cu SAPO STA-7, giving an active catalyst for the selective catalytic reduction of NOcitations
- 2011Synthesis and characterization of a series of porous lanthanide tricarboxylates
Places of action
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article
Nitric Oxide Adsorption and Delivery in Flexible MIL-88(Fe) Metal-Organic Frameworks
Abstract
Adsorption and release of the biologically active nitric oxide (NO) was evaluated over a series of highly flexible iron(III) dicarboxylate MOFs of the MIL-88 structure type, bearing fumaric or terephthalic spacer functionalized or not by polar groups (NO2. 2OH). As evidenced by ex situ X-ray powder diffraction and in situ IR spectroscopy, it appears that if the contracted dried forms of MIL-88 do not expand their structures in the presence of NO, the combination of very narrow pores and trimers of iron polyhedra leads to the adsorption of significant amounts of NO either physisorbed (very narrow pores) and/or chemisorbed [iron(II) or iron(III) coordinatively unsaturated metal sites (CUS)]. The delivery of NO under vapor of water or in simulated body fluid does not exceed 20% range of the total adsorbed amount probably due to a partial release that occurs between the adsorption/desorption setup and the chemiluminescence release tests. Some of these solids nevertheless exhibit a significant release at the biological levels over a long period of time ( h) that make these biocompatible and biodegradable MOFs of interest for the controlled release of NO.