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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sastry, Murali
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2012Ultra-low level optical detection of mercuric ions using biogenic gold nanotrianglescitations
- 2004Phase transfer of platinum nanoparticles from aqueous to organic solutions using fatty amine moleculescitations
- 2004Use of aqueous foams for the synthesis of gold nanoparticles of variable morphologycitations
- 2004A low-temperature, soft chemistry method for the synthesis of zirconia nanoparticles in thermally evaporated fatty amine thin filmscitations
- 2004One-step synthesis of ordered two-dimensional assemblies of silver nanoparticles by the spontaneous reduction of silver ions by pentadecylphenol langmuir monolayerscitations
- 2004Variation in morphology of gold nanoparticles synthesized by the spontaneous reduction of aqueous chloroaurate ions by alkylated tyrosine at a liquid-liquid and air-water interfacecitations
- 2003Assembling gold nanoparticles in solution using phosphorothioate DNA as structural interconnects
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article
Assembling gold nanoparticles in solution using phosphorothioate DNA as structural interconnects
Abstract
<p>The ordered arrangement of nanoparticles in one, two and three-dimensional structures is a problem of current interest. While assembly of nanoparticles from solution into monolayer and superlattice structures on solid surfaces has met with a fair degree of success, the controlled assembly of nanoparticles in solution remains a more difficult and relatively unexplored area. In this communication, we describe the assembly of gold nanoparticles in solution using phosphorothioate DNA as a structural interconnect. Sulphur-substituted DNA cross-links the gold nanoparticles in solution through thiolate linkages with the nanoparticle surface, and organizes them in different geometries. The small length of the phosphorothioate DNA molecules used in the study (ca. 4 nm) renders them rigid and effective as connectors between nanoparticles. The organization of gold nanoparticles by sulphur-substituted DNA has been followed with UV-vis spectroscopy, Fourier transform infrared spectroscopy and transmission electron microscopy measurements.</p>