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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kellici, Suela
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Topics
Publications (11/11 displayed)
- 20233D printed SrNbO2N photocatalyst for degradation of organic pollutants in watercitations
- 2023Nanostructured Al2O3/Graphene Additive in Bio-Based Lubricant: A Novel Approach to Improve Engine Performancecitations
- 2021Continuous hydrothermal flow synthesis of S-functionalised carbon quantum dots for enhanced oil recoverycitations
- 2018Greener synthesis of dimethyl carbonate using a novel tin-zirconia/graphene nanocomposite catalystcitations
- 2018Greener synthesis of butylene carbonate via CO2 utilisation using graphene-inorganic nanocomposite catalysts
- 2018Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalystcitations
- 2017Greener synthesis of styrene carbonate from CO2 using graphene-inorganic nanocomposite catalysts
- 2017Greener synthesis of 1, 2 butylene carbonate from CO2 using graphene-inorganic nanocomposite catalysis
- 2016Calixarene assisted rapid synthesis of silver-graphene nanocomposites with enhanced antibacterial activitycitations
- 2014Imaging the continuous hydrothermal flow synthesis of nanoparticulate CeO2 at different supercritical water temperatures using in situ angle-dispersive diffractioncitations
- 2014Optical and photocatalytic behaviours of nanoparticles in the Ti-Zn-O binary systemcitations
Places of action
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document
Greener synthesis of butylene carbonate via CO2 utilisation using graphene-inorganic nanocomposite catalysts
Abstract
The synthesis of butylene carbonate (BC) through the reaction of butylene oxide (BO) and carbon dioxide has been investigated using highly efficient graphene-inorganic heterogeneous catalyst, lathana-cerium-zirconia and graphene oxide represented as La– Ce–Zr–GO nanocomposite. The catalysts have been extensively characterised using transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) surface area measurement powder X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) analysis. Response Surface Methodology (RSM) using Box-Behnken Design (BBD) has been applied to optimise the single and interactive effect of four independent reaction variables, i.e. temperature, pressure, catalyst loading and time, on the conversion of BO and BC yield. Two quadratic regression models have been developed representing an empirical relationship between each reaction response and all the independent variables. The predicted models have been validated statistically and experimentally, where the high agreement was observed between predicted and experimental results with approximate relative errors of ±1.5% for both the conversion BO and the yield of BC.