• Danielsson, Sverker
• Öhman, Fredrik
• Lipnizki, Frank
• Holm, Richard

Abstract

Membrane filtration technique shows exclusively properties for optimized filtration for a given size, from micrometer to nanometer scales compared to other industrial filtration. However, there is a trade off in flux that has delayed the implementation of the membrane techniques for a wider range of applications. For a specific flow in a process stream, the limited flux through the membrane means large membrane area is demanded, that results in a return of investments not accepted by industry. On the other hand, as the energy prices increases and environmental issues become more and more important as design parameters, the membrane techniques will due to its excellent separation performance be of interest, and from a life cycle analysis (LCA) a feasible approach.<br/>In this project the process flows in pulp and paper sector, and in particular the waste water treatment, are studied based on membrane technology. The purpose is to obtain a procedure to evaluate the membrane technique so that the results are guiding for extended studies. Two different representative integrated mills have been in focus, one thermo-mechanical pulp mill and one kraft pulp mill. The waste water streams that result in challenges for treatment process and that due to membrane filtration give reject / accept of greater values are studied. The possible benefit is two-fold the waste can be used as a resource of added valued products and the energy demanding waste water treatment decreases.<br/>A membrane filtration equipment from Alfa LavalLabStak M20 was used in this study on different streams for a pulp and paper mill.In this unit several membranes can be tested at the same time in order to briefly evaluate a type of membrane which suitable for the prevailing conditions, ranging from RO, NF, UF and MF depending on molecular weight cut-off (MWCO) and pore size. The volume concentrations factor (VFC) ranged from 1-4 in this study and the reduced TOC indicates satisfactory results. As pointed out, a trade off in decrease flux during filtration was in the order of 20%, to be considered in process design.<br/>The result gives indication of feasible way to use membrane filtration techniques as a tool for creating new business opportunities and elucidate the potential in reducing the water and energy consumption. The technique is demonstrated to gained parameters of importance for the pulp and paper sector. However, alsoapplicable for other industry sectors when dealing with large scale processing flows<br/>

Topics

• impedance spectroscopy
• pore
• molecular weight