| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Macfarlane, Douglas
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (33/33 displayed)
- 2023High performance acidic water electrooxidation catalysed by manganese–antimony oxides promoted by secondary metalscitations
- 2018Ionic liquid electrolytes supporting high energy density in sodium-ion batteries based on sodium vanadium phosphate compositescitations
- 2018The electrochemistry and performance of cobalt-based redox couples for thermoelectrochemical cellscitations
- 2018The effect of cation chemistry on physicochemical behaviour of superconcentrated NaFSI based ionic liquid electrolytes and the implications for Na battery performancecitations
- 2017Properties of High Na-Ion Content N-Propyl-N-Methylpyrrolidinium Bis(Fluorosulfonyl)Imide -Ethylene Carbonate Electrolytescitations
- 2017Preparation and characterization of gel polymer electrolytes using poly(ionic liquids) and high lithium salt concentration ionic liquidscitations
- 2017Metal-free black silicon for solar-powered hydrogen generationcitations
- 2016Novel Na+ ion diffusion mechanism in mixed organic-inorganic ionic liquid electrolyte leading to high Na+ transference number and stable, high rate electrochemical cycling of sodium cellscitations
- 2016Reduction of oxygen in a trialkoxy ammonium-based ionic liquid and the role of watercitations
- 2016Stable zinc cycling in novel alkoxy-ammonium based ionic liquid electrolytescitations
- 2016Inorganic-organic ionic liquid electrolytes enabling high energy-density metal electrodes for energy storagecitations
- 2016Unexpected effect of tetraglyme plasticizer on lithium ion dynamics in PAMPS based ionomerscitations
- 2016Investigating non-fluorinated anions for sodium battery electrolytes based on ionic liquidscitations
- 2016In-situ-activated N-doped mesoporous carbon from a protic salt and its performance in supercapacitorscitations
- 2016Enhanced thermal energy harvesting performance of a cobalt redox couple in ionic liquid-solvent mixturescitations
- 2016Recent developments in environment-friendly corrosion inhibitors for mild steel
- 2015Spin-crossover, mesomorphic and thermoelectrical properties of cobalt(II) complexes with alkylated N3-Schiff basescitations
- 2015Evaluation of electrochemical methods for determination of the seebeck coefficient of redox electrolytescitations
- 2015Characterisation of ion transport in sulfonate based ionomer systems containing lithium and quaternary ammonium cationscitations
- 2012Electrodeposited MnOx films from ionic liquid for electrocatalytic water oxidationcitations
- 2012Electrochemical etching of aluminium alloy in ionic liquids
- 2011Anodising AA5083 aluminium alloy using ionic liquids
- 2011Electrochemical reactivity of trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate ionic liquid on glassy carbon and AZ31 magnesium alloycitations
- 2011On the use of organic ionic plastic crystals in all solid-state lithium metal batteriescitations
- 2011Anodic oxidation of AZ31 Mg alloy in ionic liquid
- 2011Crystallisation kinetics of some archetypal ionic liquidscitations
- 2011Transport properties and phase behaviour in binary and ternary ionic liquid electrolyte systems of interest in lithium batteriescitations
- 2010Potentiostatic control of ionic liquid surface film formation on ZE41 magnesium alloycitations
- 2010Long-term structural and chemical stability of DNA in hydrated ionic liquidscitations
- 2010An azo-spiro mixed ionic liquid electrolyte for lithium metal- LiFePO 4 batteriescitations
- 2010Characterization of the magnesium alloy AZ31 surface in the ionic liquid trihexyl(tetradecyl)phosphonium bis(trifluoromethanesulfonyl)amide
- 2010Proton transport properties in Zwitterion blends with Bronsted acidscitations
- 2000Experimental and theoretical investigations of the effect of deprotonation on electronic spectra and reversible potentials of photovoltaic sensitizerscitations
Places of action
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article
Recent developments in environment-friendly corrosion inhibitors for mild steel
Abstract
In 2002, our group and collaborators began initial investigations on the use of rare-earth carboxylates as non-toxic and environment-friendly corrosion inhibitors for mild steel. This was followed by a more comprehensive study, reported in 2004 by Blin et al., in which a range of such carboxylate compounds were investigated. This study identified lanthanum 4-hydroxycinnamate, La(4-OHcin)3 as a promising compound. In the review presented here our more recent investigations on mild steel corrosion inhibitors with structures closely related to La(4-OHcin)3 are presented.<br/><br/>In another study, Lee investigated the effect on corrosion of subtle changes to the La(4-OHcin)3 structure. Seter et al. found that small structural changes could have a major effect on the inhibition performance.<br/><br/>Nam et al. investigated cerium, lanthanum and praseodymium 4-hydroxycinnamate as corrosion inhibitors for mild steel in carbon dioxide atmospheres in sodium chloride solution. In this particular situation, Pr(4-OHcin)3 led to the largest reduction in corrosion current.<br/><br/>A totally organic complex, imidazolinium 4-hydroxycinnamate (Imn 4-OHcin) has been investigated with the aim of developing a compound that can inhibit both corrosion and microbial growth. This compound was found to inhibit mild steel corrosion across a wide pH range and was particularly effective at a pH of 2.<br/><br/>We have also been investigating a rare-earth compound with an alternative carboxylate structure to the cinnamate; 3-(4-methylbenzoyl)propionate(mbp). This ligand differs from 4-hydroxycinnamate by having a carbonyl group present, which may give an extra anchor point to a metal surface when forming a barrier coating. A range of rare-earth mbp complexes was investigated, with Nd(mbp)3 resulting in the largest reduction in corrosion current density at a concentration of 0.125 mM.