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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kesters, Jurgen
Hasselt University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2021Phosphonium-based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self-assembly and photovoltaic performancescitations
- 2020Phosphonium‐based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self‐assembly and photovoltaic performancescitations
- 2020Phosphonium-based polythiopheneconjugated polyelectrolytes with differentsurfactant counterions: thermal properties,self-assembly and photovoltaic performancescitations
- 2020Phosphonium-based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self-assembly and photovoltaic performances
- 2019Ladder-type high gap conjugated polymers based on indacenodithieno[3,2-b]thiophene and bithiazole for organic photovoltaicscitations
- 2018Organic and perovskite solar cells for space applicationscitations
- 2016High-Permittivity Conjugated Polyelectrolyte Interlayers for High-Performance Bulk Heterojunction Organic Solar Cellscitations
- 2016A stability study of polymer solar cells using conjugated polymers with different donor or acceptor side chain patternscitations
- 2016A stability study of polymer solar cells using conjugated polymers with different donor or acceptor side chain patternscitations
- 2015Fluorination as an effective tool to increase the open-circuit voltage and charge carrier mobility of organic solar cells based on poly(cyclopenta[2,1-b:3,4-b′]dithiophene-alt-quinoxaline) copolymerscitations
- 2015Enhanced Organic Solar Cell Stability by Polymer (PCPDTBT) Side Chain Functionalization
- 2015N-acyl-dithieno[3,2-b:2 ',3 '-d]pyrrole-based low bandgap copolymers affording improved open-circuit voltages and efficiencies in polymer solar cells
- 2015Fluorination as an effective tool to increase the open-circuit voltage and charge carrier mobility of organic solar cells based on poly(cyclopenta[2,1-b:3,4-b ']dithiophene-alt-quinoxaline) copolymerscitations
- 2015Combustion deposition of MoO3 films: from fundamentals to OPV applicationscitations
- 2015N-acyl-dithieno[3,2-b2',3'-d]pyrrole-based low bandgap copolymers affording improved open-circuit voltages and efficiencies in polymer solar cellscitations
- 2015Continuous Flow Polymer Synthesis toward Reproducible Large-Scale Production for Efficient Bulk Heterojunction Organic Solar Cellscitations
- 2014Fluorination as an effective tool to increase the open-circuit voltage and charge carrier mobility of organic solar cells based on poly(cyclopenta[2,1-b:3,4-b′]dithiophene-alt-quinoxaline) copolymerscitations
- 2014To combust or not to combust, that's the question
- 2014Enhanced open-circuit voltage in polymer solar cells by dithieno[3,2-b:2′,3′-d]pyrrole N-acylationcitations
- 2014Enhanced open-circuit voltage in polymer solar cells by dithieno[3,2-b:2 ',3 '-d]pyrrole N-acylationcitations
- 2013Ester-functionalized poly(3-alkylthiophene) copolymers: Synthesis, physicochemical characterization and performance in bulk heterojunction organic solar cellscitations
- 2013Ionic high-performance light harvesting and carrier transporting OPV materialscitations
- 2012Improved Photovoltaic Performance of a Semicrystalline Narrow Bandgap Copolymer Based on 4H-Cyclopenta[2,1-b:3,4-b ']dithiophene Donor and Thiazolo[5,4-d]thiazole Acceptor Unitscitations
Places of action
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book
Enhanced Organic Solar Cell Stability by Polymer (PCPDTBT) Side Chain Functionalization
Abstract
Organic photovoltaics represent a promising thin-film solar cell technology with appealing mechanical, aesthetical, and cost features. In recent years, a strong growth in power conversion efficiency (to over 10%) has been realized for organic solar cells through extensive material and device research. To be competitive in the renewable energy market, further improvements are mandatory though, both with respect to efficiency and lifetime. High intrinsic stability of the photoactive layer is obviously a crucial requirement for long lifetimes, but the generally applied bulk heterojunction blends and their components are prone to light-induced and thermal degradation processes. In the present contribution, the high-T-g polymer strategy is combined with specific side chain functionalization to address the thermal stability of polymer solar cells. These two design concepts are applied to a prototype low bandgap copolymer, PCPDTBT. Accelerated aging tests (at 85 degrees C) indicate an improved thermal durability of the PCPDTBT:PC71BM blends and the resulting devices by the insertion of ester or alcohol moieties on the polymer side chains. The different stages in the efficiency decay profiles are addressed by dedicated experiments to elucidate the (simultaneously occurring) degradation mechanisms. ; This work was supported by the project ORGANEXT (EMR INT4-1.2-2009-04/054), selected in the frame of the operational program INTERREG IV-A Euregio Maas-Rijn, and the IAP 7/05 project FS2 (Functional Supramolecular Systems), granted by the Science Policy Office of the Belgian Federal Government (BELSPO). We are also grateful for financial support by the Research Programme of the Research Foundation - Flanders (FWO) (project G.0415.14N and M.ERA-NET project RADESOL). J. Kesters and J. Drijkoningen thank Hasselt University for their PhD scholarships. P. Verstappen acknowledges the Agency for Innovation by Science and Technology in Flanders (IWT) for his Ph.D. grant. The authors are also grateful to B. Van Mele, N. Van den Brande, and M. Defour for the thermal analysis and H. Penxten for the CV measurements. We further acknowledge Hercules for providing the funding for the LTQ Orbitrap Velos Pro mass spectrometer. Hasselt University and IMO-IMOMEC are partners within the Solliance network, the strategic alliance for research and development in the field of thin-film PV energy in the Eindhoven-Leuven-Aachen region