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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Glarborg, Peter
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (28/28 displayed)
- 2023Investigating the Interaction between Ilmenite and Zinc for Chemical Loopingcitations
- 2023Investigating the Interaction between Ilmenite and Zinc for Chemical Loopingcitations
- 2022Thermal Conversion of Sodium Phytate Using the Oxygen Carrier Ilmenite Interaction with Na-Phosphate and Its Effect on Reactivitycitations
- 2020Experimental Investigation and Mathematical Modeling of the Reaction between SO2(g) and CaCO3(s)-containing Micelles in Lube Oil for Large Two-Stroke Marine Diesel Enginescitations
- 2019Mixed Flow Reactor Experiments and Modeling of Sulfuric Acid Neutralization in Lube Oil for Large Two-Stroke Diesel Enginescitations
- 2019Mixed Flow Reactor Experiments and Modeling of Sulfuric Acid Neutralization in Lube Oil for Large Two-Stroke Diesel Enginescitations
- 2019Kinetic Parameters for Biomass under Self-Ignition Conditions: Low-Temperature Oxidation and Pyrolysiscitations
- 2018Characterization of free radicals by electron spin resonance spectroscopy in biochars from pyrolysis at high heating rates and at high temperaturescitations
- 2018Reaction kinetics for biomass self-ignition at 150–230°C
- 2017Reaction of Sulfuric Acid in Lube Oil: Implications for Large Two-Stroke Diesel Enginescitations
- 2017Deposit Shedding in Biomass-Fired Boilers: Shear Adhesion Strength Measurementscitations
- 2017Deposit Shedding in Biomass-Fired Boilers: Shear Adhesion Strength Measurementscitations
- 2016Adhesion Strength of Biomass Ash Deposits
- 2016Adhesion Strength of Biomass Ash Deposits
- 2016Characterization of free radicals by electron spin resonance spectroscopy in biochars from pyrolysis at high heating rates and at high temperaturescitations
- 2016Characterization of free radicals by electron spin resonance spectroscopy in biochars from pyrolysis at high heating rates and at high temperaturescitations
- 2016Deposit Shedding in Biomass-fired Boilers: Shear Adhesion Strength Measurements
- 2016Deposit Shedding in Biomass-fired Boilers: Shear Adhesion Strength Measurements
- 2015Rate constant and thermochemistry for K + O2 + N2 = KO2 + N2citations
- 2015Rate constant and thermochemistry for K + O 2 + N 2 = KO 2 + N 2citations
- 2014Effect of pyrolysis conditions and composition on the char structure and char yield of biomass chars
- 2013Deposit formation in a full-scale pulverized wood-fired power plant with and without coal fly ash addition
- 2013Modeling of sulfation of potassium chloride by ferric sulfate addition during grate-firing of biomass
- 2012Deposit Probe Measurements in Danish Grate and Pulverized Fuel Biomass Power Boilers
- 2012Deposit Probe Measurements in Danish Grate and Pulverized Fuel Biomass Power Boilers
- 2012Devolatilization and Combustion of Tire Rubber and Pine Wood in a Pilot Scale Rotary Kilncitations
- 2012Combustion Aerosols from Full-Scale Suspension-Firing of Wood Pellets
- 2010Oxy-fuel combustion of solid fuelscitations
Places of action
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document
Modeling of sulfation of potassium chloride by ferric sulfate addition during grate-firing of biomass
Abstract
Potassium chloride, KCl, formed from critical ash-forming elements released during combustion may lead to severe ash deposition and corrosion problems in biomass-fired boilers. Ferric sulfate, Fe2(SO4)3 is an effective additive, which produces sulfur oxides (SO2 and SO3) to convert KCl to the less harmful K2SO4. In the present study the decomposition of ferric sulfate is studied in a fast-heating rate thermogravimetric analyzer (TGA), and a kinetic model is proposed to describe the decomposition process. The yields of SO2 and SO3 from ferric sulfate decomposition are investigated in a laboratory-scale tube reactor. It is revealed that approximately 40% of the sulfur is released as SO3, the remaining fraction being released as SO2. The proposed decomposition model of ferric sulfate is combined with a detailed gas phase kinetic model of KCl sulfation, and a simplified model of K2SO4 condensation in order to simulate the sulfation of KCl by ferric sulfate addition during grate-firing of biomass. The simulation results show good agreements with the experimental data obtained in a<br/>pilot-scale biomass grate-firing reactor, where different amounts of ferric sulfate was injected on the grate or into the freeboard. In addition, the simulations of elemental sulfur addition on the grate fit well with the experimental data. The results suggest that the SO3 released from ferric sulfate decomposition is the main contributor to KCl sulfation, and that the effectiveness of the ferric sulfate addition is sensitive to actual temperature in the system. When the ferric sulfate is injected on the grate, the majority of the released SO3 is rapidly converted to SO2 due to the high temperatures, resulting in a low effectiveness similar to that of elementary sulfur addition on the grate. On the other hand, when the ferric sulfate is injected into the freeboard where the temperatures<br/>are below 1050oC, the majority of the released SO3 contributes to the formation of K2SO4, leading to a high effectiveness in KCl destruction. Overall, the model developed in this work facilitates an optimal use of ferric sulfate in biomass combustion.