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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Steinberger-Wilckens, Robert
University of Birmingham
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (38/38 displayed)
- 2023The effects of sintering temperature and current contacting layer on the performance of lanthanum nickelate electrodes in Solid Oxide Fuel Cellscitations
- 2023Experimental and Numerical Evaluation of Polymer Electrolyte Fuel Cells with Porous Foam Distributor
- 2022Evaluation of inkjet-printed spinel coatings on standard and surface nitrided ferritic stainless steels for interconnect application in solid oxide fuel cell devicescitations
- 2022Optimization of a ScCeSZ/GDC bi-layer electrolyte fabrication process for intermediate temperature solid oxide fuel cellscitations
- 2021Five‐layer reverse tape casting of IT‐SOFCcitations
- 2020Corrosion behaviour of nitrided ferritic stainless steels for use in solid oxide fuel cell devicescitations
- 2020In-situ experimental benchmarking of solid oxide fuel cell metal interconnect solutionscitations
- 2020Scattered and linked microcracks in solid oxide fuel cell electrolyte
- 2020Electrochemical performance and carbon resistance comparison between Sn, Cu, Ag, and Rh-doped Ni/ScCeSZ anode SOFCs operated by biogas
- 2020Electrochemical performance of novel NGCO-LSCF composite cathode for intermediate temperature solid oxide fuel cellscitations
- 2020Electrochemical performance of novel NGCO-LSCF composite cathode for intermediate temperature solid oxide fuel cellscitations
- 2020Formulation of Spinel based Inkjet Inks for Protective Layer Coatings in SOFC Interconnectscitations
- 2019Non-crystallising glass sealants for SOFCcitations
- 2019Properties of 10Sc1CeSZ-3.5YSZ(33-, 40-, 50-wt.%) Composite Ceramics for SOFC Applicationcitations
- 2019Ex-situ experimental benchmarking of solid oxide fuel cell metal interconnectscitations
- 2019Ex-situ experimental benchmarking of solid oxide fuel cell metal interconnectscitations
- 2018Influence of temperature and pressure on surface modified Pd-Cu alloy foils for hydrogen purification applicationscitations
- 2018Electrochemical and thermal characterization of doped ceria electrolyte with lanthanum and zirconiumcitations
- 2018Evaluation of Inkjet Printed Protective Layer Coatings for SOFC Interconnects
- 2018X-ray diffraction study on the effects of hydrogen on Pd60Cu40 wt% foil membranescitations
- 2017Modelling Microstructural and Chemical Degradation of Ferritic Stainless Steels for SOFC Interconnects
- 2016Cu-Fe substituted Mn-Co spinels by High Energy Ball Milling for interconnect coatings: insight on sintering properties
- 2016Cu-Fe substituted Mn-Co spinels by High Energy Ball Milling for interconnect coatings: insight on sintering properties
- 2016Thin film perovskite coatings and their application for SOFC ferritic steel interconnects
- 2016Thermochemical and Kinetic Modelling of Chromium-Rich Alloys
- 2016Benchmarking Protective Coatings for SOFC ferritic steel interconnects – The SCORED 2:0 Project
- 2016Cerium-Cobalt-Copper oxides based SOFC anodes for the direct utilisation of methane as fuel
- 2015Investigating electrodes for intermediate temperature polymer electrolyte fuel cell (IT-PEFC)
- 2015Hydrogen selective membranescitations
- 2015Effects of thin film Pd deposition on the hydrogen permeability of Pd60Cu40 wt% alloy membranescitations
- 2015Status of light weight cassette design of SOFCcitations
- 2015Properties of spinel protective coatings prepared using wet powder spraying for SOFC interconnectscitations
- 2014Gas diffusion layer materials and their effect on polymer electrolyte fuel cell performance - Ex situ and in situ characterizationcitations
- 2014Cathodic materials for intermediate-temperature solid oxide fuel cells based on praseodymium nickelates-cobaltitescitations
- 2013On nucleation and growth mechanisms of EBPVD zirconia films on porous NiO-ZrO2 substrate
- 2008Reducing degradation effects in SOFC stacks manufactured at Forschungszentrum Jülich - Approaches and results
- 2005Overview of the development of solid oxide fuel cells at Forschungszentrum Juelich
- 2004Solid oxide fuel cell development at Forschungszentrum Juelich
Places of action
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document
Thermochemical and Kinetic Modelling of Chromium-Rich Alloys
Abstract
Ferritic stainless steel interconnects are critical components in Solid Oxide Fuel Cells (SOFCs), which electrically connect the cells and prevent gases from mixing. At high temperatures and in the presence of air, oxidation of the metallic interconnects leads to the formation of a passivation scale of chromium oxide. The growing thickness of the scale increases the electrical contact resistance of the interconnects and the formation of volatile chromium species lead to chromium poisoning in the cathode. It is therefore critically<br/>important for the estimation of the lifetime of SOFCs to investigate these degradation mechanisms which affect the long-term output cell voltage.<br/>This study examines the high temperature oxidation behavior in conventional ferritic stainless steel (FeCr) interconnects, using thermodynamic and kinetic modelling approaches. The first stage of the study involves designing a coupled one-dimensional thermodynamic-kinetic oxidation and diffusion model. This model is based on the simultaneous thermodynamic assessment of oxidation reactions and calculation of scale growth kinetics, using a finite difference numerical method.<br/>The expected results allow to predict the composition profile in the alloy, as well as the thickness of the oxide layer formed as a function of oxidation time. This model will serve as a basis for life-time prediction of a manganese and cobalt spinel protective layer coated FeCr interconnect in the second stage of the study.