| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Hryha, Eduard
Chalmers University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (39/39 displayed)
- 2024On the Origin of Enhanced Tempering Resistance of the Laser Additively Manufactured Hot Work Tool Steel in the As-Built Conditioncitations
- 2024Full Density Powder Metallurgical Cold Work Tool Steel through Nitrogen Sintering and Capsule-Free Hot Isostatic Pressingcitations
- 2024Machining of additively manufactured alloy 718 in as-built and heat-treated condition: surface integrity and cutting tool wearcitations
- 2024Machining of additively manufactured alloy 718 in as-built and heat-treated condition : surface integrity and cutting tool wearcitations
- 2024Machining of additively manufactured alloy 718 in as-built and heat-treated condition : surface integrity and cutting tool wearcitations
- 2024Fine-Tuning Melt Pools and Microstructures: Taming Cracks in Powder Bed Fusion—Laser Beam of a non-weldable Ni-base Superalloycitations
- 2023Effect of layer thickness on spatter properties during laser powder bed fusion of Ti-6Al-4Vcitations
- 2023Machining of additively manufactured alloy 718 in as-built and heat-treated condition : surface integrity and cutting tool wearcitations
- 2022In situ tempering of martensite during laser powder bed fusion of Fe-0.45C steelcitations
- 2021The role of microstructural characteristics of additively manufactured Alloy 718 on tool wear in machiningcitations
- 2020Effect of atomization on surface oxide composition in 316L stainless steel powders for additive manufacturingcitations
- 2020Full Densification in PM Steels Through Liquid Phase Sintering and HIP Approach
- 2018High temperature oxidation behavior of DMLS produced Inconel 625
- 2018Enhanced Densification of PM Steels by Liquid Phase Sintering with Boron-Containing Master Alloycitations
- 2015Nitrogen uptake of nickel free austenitic stainless steel powder during heat treatment : an XPS study
- 2015Influence of the PM-processing route and nitrogen content on the properties of Ni-free austenitic stainless steel
- 2015Thermodynamic And Kinetic Aspects Of Oxide Transformation During Sintering Of Cr-Prealloyed Pm Steels
- 2014EFFICIENCY AND TEMPERATURE RANGES OF ACTIVITY OF DIFFERENT REDUCING AGENTS DURING SINTERING OF CR-PREALLOYED PM STEELS
- 2014APPLICATION OF FRACTOGRAPHY FOR INVESTIGATION OF SURFACE OXIDE REDUCTION/TRANSFORMATION AND INTER-PARTICLE NECKS FORMATION DURING SINTERING OF PREALLOYED WITH Cr AND Mn PM STEELS
- 2014Surface Oxides on Gas and Water Atomized Steel Powders
- 2014Microstructure Development in Powder Metallurgy Steels: Effect of Alloying Elements and Process Variables
- 2014Oxide Transformation in Cr-Mn-Prealloyed Sintered Steels: Thermodynamic and Kinetic Aspects
- 2014Thermogravimetry Study of the Effectiveness of Different Reducing Agents during Sintering of Cr-prealloyed PM Steels
- 2014THERMODYNAMIC AND KINETIC ASPECTS OF OXIDE TRANSFORMATION DURING SINTERING OF CR-PREALLOYED PM STEELS
- 2014Effectiveness of reducing agents during sintering of Cr-prealloyed PM steels
- 2013Effect of reducing agents on the sintering of chromium alloyed PM steels
- 2013Characteristics of Surface Oxides: Similarities and Differences between Gas and Water Atomized Steel Powders
- 2013Surface Oxides on Gas and Water Atomized Steel Powders
- 2013Parameters Controlling the Oxide Reduction during Sintering of Chromium Prealloyed Steelcitations
- 2013Effect of Processing Parameters on Oxide Transformation in Cr-Mn-Prealloyed Sintered Steels
- 2013Effectiveness of Different Reducing Agents during Sintering of Cr-Prealloyed PM Steels
- 2013Optimisation of sintering atmospheres for controlled sintering of PM steels
- 2012Influence of nitrogen atmosphere on reduction mechanisms of a high strength austenitic steel
- 2012Process Control System for Delubrication of PM Steels
- 2011Oxide Transformation during Sintering of Cr and Mn Prealloyed Water Atomized Steel Powder
- 2011Characterization of high-Mn-Cr austenitic steel powder Fe-19Mn-18Cr-C-N
- 2011CHANGES IN OXIDE CHEMISTRY DURING CONSOLIDATION OF Cr/Mn WATER ATOMIZED STEEL POWDER
- 2011The Sintering Behaviour of Fe-Mn-C Powder System, Correlation between Thermodynamics and Sintering Process, Manganese Distribution and Microstructure Composition, Effect of Alloying Mode
- 2010Oxide Transformation During Sintering Of Prealloyed Water Atomized Steel Powder
Places of action
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article
Oxide Transformation in Cr-Mn-Prealloyed Sintered Steels: Thermodynamic and Kinetic Aspects
Abstract
The main obstacle for utilization of Cr and Mn as alloying elements in powder metallurgy is their high oxygen affinity leading to oxidation risk during powder manufacturing, handling, and especially during further consolidation. Despite the high purity of the commercially available Cr- and Mn-prealloyed iron powder grades, the risk of stable oxide formation during the sintering process remains. Thermodynamic and kinetic simulation of the oxide formation/transformation on the former powder surface during heating and sintering stages using thermodynamic modeling tools (Thermo-Calc and HSC Chemistry) was performed. Simulation is based on the results from the analysis of amount, morphology, and composition of the oxide phases inside the inter-particle necks in the specimens from interrupted sintering trials utilizing advanced analysis tools (HRSEM + EDX and XPS). The effect of the processing parameters, such as sintering atmosphere composition, temperature profile as well as graphite addition on the possible scenarios of oxide reduction/formation/transformation for Fe-Cr-Mn-C powder systems, was evaluated. Results indicate that oxide transformation occurs in accordance with the thermodynamic stability of oxides as follows: Fe2O3 -> FeO -> Fe2MnO4 -> Cr2FeO4 -> Cr2O3 -> MnCr2O4 -> MnO/MnSiO (x) -> SiO2. Spinel MnCr2O4 was identified as the most stable oxide phase at applied sintering conditions up to 1393 K (1120 A degrees C). Controlled conditions during the heating stage minimize the formation of stable oxide products and produce oxide-free sintered parts.