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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Fantozzi, Davide
Tampere University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2021Chlorine-induced High Temperature Corrosion of Thermally Sprayed Coatings
- 2019Chlorine induced high-temperature corrosion mechanisms in HVOF and HVAF sprayed Cr3C2-based hardmetal coatingscitations
- 2018Arc-sprayed Fe-based coatings from coredwires for wear and corrosion protection in power engineeringcitations
- 2018Chlorine-Induced High Temperature Corrosion of Inconel 625 Sprayed Coatings Deposited with Different Thermal Spray Techniquescitations
- 2018High Temperature Corrosion and Erosion Properties of Thermally Sprayed Ceramic Oxide Coatings
- 2018Effect of Carbide Dissolution on Chlorine Induced High Temperature Corrosion of HVOF and HVAF Sprayed Cr3C2-NiCrMoNb Coatingscitations
- 2018High temperature corrosion properties of thermally sprayed ceramic oxide coatings
- 2017Properties of arc-sprayed coatings from Fe-based cored wires for high-temperature applications
- 2017Effect of Carbide Dissolution in the Metal Matrix of HVOF and HVAF Sprayed Cr3C2-NiCrMoNb Coatings on the Initial Stage of Chlorine High Temperature Corrosion
- 2017Chlorine-Induced High Temperature Corrosion of Inconel 625 Sprayed Coatings Deposited with Different Thermal Spray Techniquescitations
- 2015Fatigue behaviour of nickel- and cobalt-based laser cladded coatings on steel bars
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document
Effect of Carbide Dissolution in the Metal Matrix of HVOF and HVAF Sprayed Cr3C2-NiCrMoNb Coatings on the Initial Stage of Chlorine High Temperature Corrosion
Abstract
Highly corrosion and wear resistant thermally sprayed chromium carbide (Cr3C2) based cermets coatings are nowadays a potential highly durable solution to allow traditional fluidised bed combustors (FBC) to be operated with ecological waste and biomass fuels. However, the heat input of thermal spraying processes causes carbide dissolution in the metal binder. This alters the coating structure and forms carbon saturated amorphous and nanocrystalline metastable areas, which can affect the behaviour of the materials under the corrosive chlorides containing environment of the flue gases. This study analyses the effect of carbide dissolution in the metal matrix of MMC coatings and its effect on the onset of chlorine induced high temperature corrosion. Four Cr3C2-NiCrMoNb coatings were thermally sprayed with high-velocity air-fuel (HVAF) and high-velocity oxygen-fuel (HVOF) spray processes in order to obtain microstructures with increasing amount of carbide dissolution in the metal matrix. The <br/>specimens were heat treated in an inert argon atmosphere at 700˚C for 5 hours to induce secondary carbide precipitation. As-sprayed and heat-treated self-standing coatings were covered with KCl and their corrosion resistance was investigated with thermogravimetric analysis (TGA) at 550˚C for 4 hours. High carbon dissolution in the metal matrix appeared to be a detrimental factor in the initial stage of corrosion. The microstructural changes induced by the heat treatment hindered the corrosion onset in the coatings. Moreover, an optimal amount of oxides <br/>and melting degree seemed beneficial.