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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rath, Thomas
Graz University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Silicon and Germanium Functionalized Perylene Diimides – Synthesis, Optoelectronic Properties, and their Application as Non-Fullerene Acceptors in Organic Solar Cellscitations
- 2023Solution-Processable Cu3BiS3 Thin Films: Growth Process Insights and Increased Charge Generation Properties by Interface Modificationcitations
- 2023The challenge with high permittivity acceptors in organic solar cells: a case study with Y-series derivativescitations
- 2023Bio-Polyester/Rubber Compounds: Fabrication, Characterization, and Biodegradationcitations
- 2023Low-cost and automated phenotyping system “Phenomenon” for multi-sensor in situ monitoring in plant in vitro culturecitations
- 2022Glycol bearing perylene monoimide based non-fullerene acceptors with increased dielectric permittivitycitations
- 2020Cellulose metal sulfide based nanocomposite thin films
- 2020Synthesis and characterization of zinc di(O-2,2-dimethylpentan-3-yl dithiocarbonates) bearing pyridine or tetramethylethylenediamine coligands and investigation of their thermal conversion mechanisms towards nanocrystalline zinc sulfidecitations
- 2019Multi-layered nanoscale cellulose/CuInS2 sandwich type thin filmscitations
- 2019Modification of NiOx hole transport layers with 4-bromobenzylphosphonic acid and its influence on the performance of lead halide perovskite solar cellscitations
- 2017Progress on lead-free metal halide perovskites for photovoltaic applications: a reviewcitations
- 2016Solution-Processed Bismuth(III)-Based Halide Perovskites as Absorber Materials for Photovoltaic Applications
- 2016Influence of Polymer Phase, Polymer/Nanoparticle Ratio and Organic Additives on the Performance of Hybrid Solar Cells
- 2013Bismuth sulphide–polymer nanocomposites from a highly soluble bismuth xanthate precursorcitations
- 2012Comprehensive Investigation of Silver Nanoparticle/Aluminum Electrodes for Copper Indium Sulfide/Polymer Hybrid Solar Cellscitations
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document
Solution-Processed Bismuth(III)-Based Halide Perovskites as Absorber Materials for Photovoltaic Applications
Abstract
Bismuth(III) halide perovskites are promising alternative absorber materials to commonly used organolead- and organotin-based perovskites due to the low toxicity and ambient stability.<sup>[1]</sup> In this work, hybrid organic-inorganic bismuth(III) halide perovskites based on methylammonium (CH<sub>3</sub>NH<sub>3</sub><sup>+</sup>, MA<sup>+</sup>) as A-site cation and halide counter ions (I<sup>-</sup>, Cl<sup>-</sup>) incorporated on the X-site of the perovskite structure were investigated using bismuth(III) halides (BiI<sub>3</sub>, BiCl<sub>3</sub>) and methylammonium iodide (MAI) as starting compounds. The perovskite absorber materials (MA<sub>3</sub>Bi<sub>2</sub>I<sub>9</sub>, MA<sub>3</sub>Bi<sub>2</sub>I<sub>9-x</sub>Cl<sub>x</sub>) were prepared in a low-temperature solution-based processing route following a one-step and two-step procedure.<sup>[2,3]</sup> The absorber materials were evaluated with regard to their photovoltaic performance in organic (PEDOT:PSS) as well as in planar (c-TiO<sub>2</sub>) and meso-structured (c-TiO<sub>2</sub>/mp-TiO<sub>2</sub>) perovskite solar cell architecture (Fig. 1). In addition, the perovskites were characterized optically (UV/VIS spectroscopy, light microscopy), structurally (X-ray diffraction), andmorphologically (atomic force microscopy).