• Gigot, Arnaud Nicolas
• Marasso, Sl
• Enrico, Alessandro
• Rivolo, Paola
• Giardi, R.
• Tresso, Elena Maria
• Pirri, Cf
• Serrapede, Mara
• Benetto, Simone
• Cocuzza, Matteo
• Mombello, D.

Abstract

In this work a hybrid graphene-based flexible micro-supercapacitor (MSC) exploiting a novel composite material was fabricated and extensively characterized. TheMSCelectrodes have been obtained from a synthesized composite aerogel of reduced graphene oxide and polycrystalline nanoparticles of molybdenum (IV) oxide (MoO2) and then dispersed in a solution containing poly(3,4-ethylenedioxythiophene) (PEDOT). Usually in MSCs the electrons have to percolate through the nanostructured Three-dimensional (3D) matrix in order to reach the collectors, made by metal thin films that provide electrical contacts only on the surface of active material. In the attempt to enable a more efficient charge transfer and to allow direct electrical contact without metal deposition, in this study a highly doped PEDOT acting both as current collector and as binder for the nanocomposite material has been employed. 3D MSCs were fabricated through a Lithographie, Galvanoformung, Abformung (LIGA)-like process to obtain high aspect ratio microstructures in polydimethylsiloxane replicas. Capacitance values of 94 F g1 for the nanocomposite and of 14 mF cm-2 for the device were achieved. Moreover, bending test has demonstrated good performance preservation in aUshape conformation of the device.

Topics

• nanoparticle
• Deposition
• nanocomposite
• microstructure
• surface
• molybdenum
• polymer
• thin film
• bending flexural test