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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Gill, H. S.
University of Bath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Experiments and numerical modelling of secondary flows of blood and shear-thinning blood analogue fluids in rotating domainscitations
- 2024Auxetic fixation devices can achieve superior pullout performances compared to standard fixation conceptscitations
- 2021Properties of PMMA end cap holders affect FE stiffness predictions of vertebral specimens
- 20213D Printed Medical Grade Ti-6Al-4V Osteosynthesis Devices Meet the Requirements for Tensile Strength, Bending, Fatigue and Biocompatibility
- 2019Evaluating strength of 3D printed screw threads for patient-specific osteosynthesis plates
- 2019Evaluation of optimised cervical spine viscoelastic elements for sport injury analysis
- 2018The effect of plate design, bridging span, and fracture healing on the performance of high tibial osteotomy plates – an experimental and finite element study.citations
- 2017Validated cemented socket model for optimising acetabular fixation
- 2017Effect of absorbed fatty acids on physical properties of ultra-high molecular weight polyethylene
- 2017Use of contrast agents on polymeric materials
- 2016A Python Package to Assign Material Properties of Bone to Finite Element Models from within Abaqus Software
- 2016An open source software tool to assign the material properties of bone for ABAQUS finite element simulationscitations
- 2016A validated specimen specific finite element model of vertebral body failure
- 2016Variations in Cortical Thickness of Composite Femur Test Specimens
- 2015Tibial Fracture after Unicompartmental Knee Replacement: The Importance of Surgical Cut Accuracy
- 2014Classification of retinal ganglion cells in the southern hemisphere lamprey Geotria australis (Cyclostomata)citations
- 2014Effect of Q-switched laser surface texturing of titanium on osteoblast cell response
- 2013Fracture of mobile unicompartmental knee bearingscitations
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document
Effect of absorbed fatty acids on physical properties of ultra-high molecular weight polyethylene
Abstract
Studies have demonstrated fatty acids diffuse into ultra-high molecular weight polyethylene (UHMWPE) prosthetic components (Costa, Biomaterials, 2001), but their effect on the physical properties remains poorly understood. One of the main fatty acids present in synovial fluid is octadecadienoic acid. We compared the properties of UHMWPE tensile test samples doped with <i>cis</i>-9,<i>cis</i>-12-Octadecadienoic acid (Sigma Aldrich) for 24 h at 100 <sup>o</sup>C to control samples heated to 100 <sup>o</sup>C for 24 h in air. Both cross-sectional area and weight increased after doping (area increase: 1.3% &plusmn 0.2, weight increase: 3% &plusmn 0.28). Infrared spectroscopy (Perkin-Elmer Frontier with ATR, 32 scans, from 4000 to 600 cm<sup>-1</sup>) confirmed the presence of octadecadienoic acid (peak at 309 cm<sup>-1</sup>). Differential scanning calorimetry results showed doping significantly decreased the crystallinity (p=0.015, n=3) and the melting temperature (p=0.001, n=3).Tensile tests (n=5) were carried out in accordance with ISO527 using an electromechanical testing machine (Instron 5965) and a contact extensometer, at a rate of 50 mm/min.The doped samples had significantly lower yield stress (p&lt0.0001) and elongation at failure (p=0.03), but no change was found in modulus or ultimate stress. The results demonstrate the absorption of octadecadienoic acid, which happens over time <i>in vivo</i>, alters UHMWPE dimensions, reduces crystallinity, melting temperature, yield stress, and elongation at failure. Consequently, it is important that the effect of fatty acid absorption is taken into account when performing <i>in vitro</i> tests of UHMWPE components, such as wear testing.The dimensional change also has implications for close fitting component designs.