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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Virtanen, Suvi
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2019Understanding the cross-linking reactions in highly oxidized graphene/epoxy nanocomposite systemscitations
- 2016Dielectric breakdown strength and electrical conductivity of low density polyethylene octylnanosilica composite
- 2015Large-area dielectric breakdown performance of polymer films:Part II: Interdependence of filler content, processing and breakdown performance in polypropylene-silica nanocompositescitations
- 2015Bimodal dielectric nanoparticles and nanocomposites
- 2015Balanced nanocomposite thermosetting materials for HVDC and AC applications
- 2014Structure and dielectric breakdown strength of nano calcium carbonate/polypropylene compositescitations
- 2014Improved dielectric breakdown strength using bimodal functionalized silica nanoparticles
- 2014Dielectric breakdown strength of epoxy bimodal-polymer-brush-grafted core functionalized silica nanocompositescitations
- 2014Influence of low amounts of nanostructured silica and calcium carbonate fillers on the large-area dielectric breakdown performance of bi-axially oriented polypropylenecitations
- 2013Structural studies of dielectric polymer nanocomposites
- 2011Characterization of octamethylsilsesquioxane (CH3)8Si8O12 fillers in polypropene matrix
- 2010Dielectric properties and partial discharge endurance of polypropylene-silica nanocompositecitations
Places of action
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conferencepaper
Dielectric breakdown strength and electrical conductivity of low density polyethylene octylnanosilica composite
Abstract
One challenge in studying nanodielectric composites is to produce reliable, reproducible samples. A common strategy to suppress aggregation and make the particles more compatible with the polymer matrix is to modify the nanoparticle surface chemistry but, often, evaluation of the effectiveness of the chosen surface functionalization process can prove difficult. In this paper the emphasis is on feasible ways to monitor the production of silane coupled nanosilica low density polyethylene (LDPE) composites, using Fourier transform infrared spectroscopy (FTIR) and thermal gravimetric analysis (TGA). The AC-breakdown properties of the resulting composites is studied and the field dependency of the DC-conductivity is measured and also calculated using a space charge limited conduction (SCLC) model together with densities of states obtained from ab initio calculations. For composites containing 13 wt% of nanosilica, breakdown strengths some 18 % higher than that of the unfilled LDPE were obtained. However, the results are not stable over time. This appears to be related to how extensively the composite is dried at elevated temperatures under vacuum.