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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Keskinen, Jari
Tampere University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2025Enhancing specific capacitance and energy density in printed supercapacitors : The role of activated wood carbon and electrolyte dynamicscitations
- 2024Flexible screen-printed supercapacitors with asymmetric PANI/CDC–AC electrodes and aqueous electrolytecitations
- 2024Recyclability of novel energy harvesting and storage technologies for IoT and wireless sensor networkscitations
- 2024Monolithic supercapacitors prepared by roll-to-roll screen printingcitations
- 2023Wear reliability and failure mechanism of inkjet-printed conductors on paperboard substratecitations
- 2023Screen printable PANI/carbide-derived carbon supercapacitor electrode ink with chitosan bindercitations
- 2019Motion energy harvesting and storage system including printed piezoelectric film and supercapacitorcitations
- 2016Conformal titanium nitride in a porous silicon matrix: A nanomaterial for in-chip supercapacitorscitations
- 2016Conformal titanium nitride in a porous silicon matrix: A nanomaterial for in-chip supercapacitorscitations
- 2007Processing of Raney-nickel catalysts for alkaline fuel cell applicationscitations
- 2006Improved mechanical properties by nanoreinforced HVOF-sprayed ceramic composite coatings
- 2006Process optimization for nanostructured HVOF -sprayed Al2O 3-based ceramic coatings
- 2006Process optimization for nanostructured HVOF-sprayed Al2O3-based ceramic coatingscitations
- 2006Development of nano-reinforced HVOF sprayed ceramic coatingscitations
- 2006Development of nanostructured Al2O3-Ni HVOF coatingscitations
- 2006Parameter optimization of HVOF sprayed nanostructured alumina and alumina-nickel composite coatingscitations
- 2006Process optimization for nanostructured HVOF -sprayed Al2O3-based ceramic coatingscitations
- 2006Development of nanostructured Al2O3-NiHVOFcoatings
- 2005Comparison of modeling and experimental results of modified Pt-based PEMFC cathode-catalysts
- 2005Process optimization and performance of nanoreinforced HVOF-sprayed ceramic coatings
- 2005Processing of R-nickel catalysts for alkaline fuel cell applications
- 2002Comparison of modeling and experimental results of modified Pt-based PEMFC cathode-catalysts
- 2001Synthesis of silver powder using a mechanochemical processcitations
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document
Comparison of modeling and experimental results of modified Pt-based PEMFC cathode-catalysts
Abstract
<p>Pt-based binary and ternary alloy catalysts were investigated by modeling methods and experimentally. The lattice parameters Of Pt, Pt3Cr, Pt3CO, Pt3Ir, Pt2CoCr, Pt2CoIr, Pt2Cr2 and Pt2Co2 were determined by molecular modeling methods. According to the optimized structures, the most typical crystal faces were generated. In order to get a good description of sterical and electrostatic factors of material surfaces, reconstruction of surface atoms was taken into account. It was shown that the alloying of Pt with base metals affect surface charge densities, which enables steering of surface reactions into desired positions on the catalyst surface. Both commercial (E-TEK) and laboratory-made catalyst powders and inks based on Pt:Co/C and Pt:Co:Cr/C were characterized voltammetrically. The active Pt surface area increased after activating the catalyst. This can most likely be attributed to the dissolving of Co and Cr from the alloys. All laboratory-made catalysts were also characterized by XRD, TEM and STEM/EDS.</p>