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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dai, Sheng
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2023Mechanical and creep properties of granitic minerals of albite, biotite, and quartz at elevated temperaturecitations
- 2021Insight into the Solid Electrolyte Interphase Formation in Bis(fluorosulfonyl)Imide Based Ionic Liquid Electrolytescitations
- 2019Decoupling the roles of carbon and metal oxides on the electrocatalytic reduction of oxygen on La1-xSrxCoO3-d perovskite composite electrodescitations
- 2018Smart Pd Catalyst with Improved Thermal Stability Supported on High-Surface-Area LaFeO3Prepared by Atomic Layer Depositioncitations
- 2014Anion charge storage through oxygen intercalation in LaMnO3 perovskite pseudocapacitor electrodescitations
- 2009Not All Anionic Polyelectrolytes Complex with DTAB
Places of action
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article
Not All Anionic Polyelectrolytes Complex with DTAB
Abstract
The influence of hydroxypropyl guar (HPG), with and without boric acid, on dodecyltrimethyl ammonium bromide (DTAB) micellization was characterized by surface tension measurements, isothermal titration calorimetry, and small-angle neutron scattering. Although HPG is a nonionic water-soluble polymer, borate ions form weak bonds with HPG, transforming it into ail anionic polyelectrolyte, HPG-borate. Surprisingly, the three independent measurements showed that HPG-borate does not promote DTAB micellization or phase separation normally seen when mixing oppositely charged polyelectrolytes and surfactants. However, the neutron scattering results suggested that HPG-borate binds to and flocculates existing DTAB micelles. The unusual behavior of HPG-borate with DTAB was underscored by showing that carboxymethyl guar (CMG) formed precipitates with DTAB ; The influence of hydroxypropyl guar (HPG), with and without boric acid, on dodecyltrimethyl ammonium bromide (DTAB) micellization was characterized by surface tension measurements, isothermal titration calorimetry, and small-angle neutron scattering. Although HPG is a nonionic water-soluble polymer, borate ions form weak bonds with HPG, transforming it into ail anionic polyelectrolyte, HPG-borate. Surprisingly, the three independent measurements showed that HPG-borate does not promote DTAB micellization or phase separation normally seen when mixing oppositely charged polyelectrolytes and surfactants. However, the neutron scattering results suggested that HPG-borate binds to and flocculates existing DTAB micelles. The unusual behavior of HPG-borate with DTAB was underscored by showing that carboxymethyl guar (CMG) formed precipitates with DTAB