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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Li, Qingfeng
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (28/28 displayed)
- 2022Feasibility of using thin polybenzimidazole electrolytes in high-temperature proton exchange membrane fuel cellscitations
- 2022Feasibility of using thin polybenzimidazole electrolytes in high-temperature proton exchange membrane fuel cellscitations
- 2020Polybenzimidazole-Based High-Temperature Polymer Electrolyte Membrane Fuel Cells: New Insights and Recent Progresscitations
- 2020Polybenzimidazole-Based High-Temperature Polymer Electrolyte Membrane Fuel Cells: New Insights and Recent Progresscitations
- 2020From polybenzimidazoles to polybenzimidazoliums and polybenzimidazolidescitations
- 2020Process for producing metal alloy nanoparticles
- 2019Thermally crosslinked sulfonated polybenzimidazole membranes and their performance in high temperature polymer electrolyte fuel cellscitations
- 2019Dynamics of double-pulse laser printing of copper microstructurescitations
- 2018Long-Term Durability of PBI-Based HT-PEM Fuel Cells: Effect of Operating Parameterscitations
- 2016Amino-Functional Polybenzimidazole Blends with Enhanced Phosphoric Acid Mediated Proton Conductivity as Fuel Cell Electrolytescitations
- 2016Amino-Functional Polybenzimidazole Blends with Enhanced Phosphoric Acid Mediated Proton Conductivity as Fuel Cell Electrolytescitations
- 2016Guanidinium nonaflate as a solid-state proton conductorcitations
- 2016Zero-Gap Alkaline Water Electrolysis Using Ion-Solvating Polymer Electrolyte Membranes at Reduced KOH Concentrationscitations
- 2016Zero-Gap Alkaline Water Electrolysis Using Ion-Solvating Polymer Electrolyte Membranes at Reduced KOH Concentrationscitations
- 2015The effect of preparation method on the proton conductivity of indium doped tin pyrophosphatescitations
- 2015Lowering the platinum loading of high temperature polymer electrolyte membrane fuel cells with acid doped polybenzimidazole membranescitations
- 2014Hydrogen evolution activity and electrochemical stability of selected transition metal carbides in concentrated phosphoric acidcitations
- 2014Hydrogen evolution activity and electrochemical stability of selected transition metal carbides in concentrated phosphoric acidcitations
- 2014Intermediate Temperature Steam Electrolysis with Phosphate-Based Electrolytes
- 2014Invited: A Stability Study of Alkali Doped PBI Membranes for Alkaline Electrolyzer Cells
- 2014Polybenzimidazole and sulfonated polyhedral oligosilsesquioxane composite membranes for high temperature polymer electrolyte membrane fuel cellscitations
- 2014Physicochemical properties of 1,2,4-triazolium perfluorobutanesulfonate as an archetypal pure protic organic ionic plastic crystal electrolyte
- 2014High Surface Area Tungsten Carbides: Synthesis, Characterization and Catalytic Activity towards the Hydrogen Evolution Reaction in Phosphoric Acid at Elevated Temperatures
- 2014High Surface Area Tungsten Carbides: Synthesis, Characterization and Catalytic Activity towards the Hydrogen Evolution Reaction in Phosphoric Acid at Elevated Temperatures
- 2013Catalyst Degradation in High Temperature Proton Exchange Membrane Fuel Cells Based on Acid Doped Polybenzimidazole Membranescitations
- 2011Oxidative degradation of polybenzimidazole membranes as electrolytes for high temperature proton exchange membrane fuel cellscitations
- 20101.7 nm Platinum Nanoparticles: Synthesis with Glucose Starch, Characterization and Catalysiscitations
- 2001Phosphoric acid doped polybenzimidazole membranes: Physiochemical characterization and fuel cell applications [PEM fuel cells]
Places of action
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article
Phosphoric acid doped polybenzimidazole membranes: Physiochemical characterization and fuel cell applications [PEM fuel cells]
Abstract
A polymer electrolyte membrane fuel cell operational at temperatures around 150-200 degrees C is desirable for fast electrode kinetics and high tolerance to fuel impurities. For this purpose polybenzimidazole (PBI) membranes have been prepared and H/sub 3/PO/sub 4/-doped in a doping range from 300 to 1600 mol%. Physiochemical properties of the membrane electrolyte have been investigated by measurements of water uptake, acid doping level, electric conductivity, mechanical strength and water drag coefficient. Electrical conductivity is found to be insensitive to humidity but dependent on the acid doping level. At 160 degrees C a conductivity as high as 0.13 S cm/sup -1/ is obtained for membranes of high doping levels. Mechanical strength measurements show, however, that a high acid doping level results in poor mechanical properties. At operational temperatures up to 190 degrees C, fuel cells based on this polymer membrane have been tested with both hydrogen and hydrogen containing carbon monoxide.