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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mauro, J. C.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Mixed metal node effect in zeolitic imidazolate frameworkscitations
- 2019Understanding Glass through Differential Scanning Calorimetrycitations
- 2018Compositional Dependence of Solubility/Retention of Molybdenum Oxides in Aluminoborosilicate-Based Model Nuclear Waste Glassescitations
- 2014A model for phosphate glass topology considering the modifying ion sub-networkcitations
- 2014Modifier constraints in alkali ultraphosphate glassescitations
- 2014On the origin of the mixed alkali effect on indentation in silicate glassescitations
- 2012Topological Principles of Borosilicate Glass Chemistry - An Invited Talk
- 2012Structure and Properties of Compressed Borate Glasses
- 2012Hardness and crack behavior of compressed borate glasses
- 2011Topological Principles of Borosilicate Glass Chemistrycitations
Places of action
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conferencepaper
Structure and Properties of Compressed Borate Glasses
Abstract
While the influence of thermal history on the structure and properties of glasses has been thoroughly studied in the past century, the influence of pressure history has received considerably less attention. In this study, we investigate the pressure-induced changes in structure and properties in a series of borate glasses. Upon isostatic compression, NMR experiments show that the fraction of tetrahedral boron increases, leading to an overall decrease of the molar volume of the network. We correlate these structural changes with changes in elastic moduli from Brillouin scattering experiments, hardness and crack formation from nanoindentation experiments, and overshoot in isobaric heat capacity from DSC experiments at ambient pressure. The influence of the initial boron speciation on the degree of changes in structure and properties will also be discussed. ; While the influence of thermal history on the structure and properties of glasses has been thoroughly studied in the past century, the influence of pressure history has received considerably less attention. In this study, we investigate the pressure-induced changes in structure and properties in a series of borate glasses. Upon isostatic compression, NMR experiments show that the fraction of tetrahedral boron increases, leading to an overall decrease of the molar volume of the network. We correlate these structural changes with changes in elastic moduli from Brillouin scattering experiments, hardness and crack formation from nanoindentation experiments, and overshoot in isobaric heat capacity from DSC experiments at ambient pressure. The influence of the initial boron speciation on the degree of changes in structure and properties will also be discussed.