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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mirzaeian, Mojtaba
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2022Development of functional materials for the removal of heavy metals from industrial waste waters
- 2022Graphene synthesis techniques and environmental applicationscitations
- 2022Structural tuneability and electrochemical energy storage applications of resorcinol-formaldehyde-based carbon aerogelscitations
- 2020Effect of physical activation/surface functional groups on wettability and electrochemical performance of carbon/activated carbon aerogels based electrode materials for electrochemical capacitorscitations
- 2020Pseudocapacitive effect of carbons doped with different functional groups as electrode materials for electrochemical capacitorscitations
- 2019Effect of nitrogen doping on the electrochemical performance of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applicationscitations
- 2018Synthesis and characterisation of control porosity resorcinol formaldehyde based carbon aerogels under different conditions
- 2018Effect of nitrogen doping on physical and electrochemical properties of resorcinol / formaldehyde based carbons
- 2017Synthesis and electrochemical properties of highly porous nitrogen-doped carbon for improved supercapacitor performance
- 2017Improving the functionality of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applications
- 2017Electrochemical performance of controlled porosity resorcinol/formaldehyde based carbons as electrode materials for supercapacitor applicationscitations
- 2015The Effect of Growth Conditions on the Surface Energy, Optical Properties and Saline Corrosion Resistance of Amorphous Chromium Oxide Thin Films Prepared by Reactive Magnetron Sputtering
- 2010Study of structural change in Wyodak coal in high pressure CO2 by small-angle neutron scatteringcitations
- 2009The control of porosity at nano scale in resorcinol formaldehyde carbon aerogelscitations
- 2009Preparation of controlled porosity carbon-aerogels for energy storage in rechargeable lithium oxygen batteriescitations
- 2008Thermodynamical studies of irreversible sorption of CO2 by Wyodak coal
- 2007High capacity carbon based electrodes for lithium/oxygen batteries
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document
Synthesis and characterisation of control porosity resorcinol formaldehyde based carbon aerogels under different conditions
Abstract
Highly porous carbon aerogels are synthesised by sol-gel polymerisation of resorcinol (R) and formaldehyde (F) using sodium carbonate (C) as catalyst followed by carbonization under steady flow of argon (Ar). The effect of resorcinol / catalyst (R/C) ratio and carbonization temperature on the porous structure of resultant gels and carbons was investigated using nitrogen adsorption-desorption measurements at -196 ºC. By controlling the R/C ratio between 100-500 and carbonization temperature between 800-100 ºC, carbon aerogels with specific surface area (SSA) ranging between 537-687 m2 g-1 and average pore size in the of 1.80 - 4.62 nm can be produced. it has been shown that carbonization had significant effect on the porous structure of the resultant carbon aerogels, decreasing the pore size and increasing the microporosity of the carbon due to the shrinkage of the nanostructure and the formation of microporosity within the gel structure. Substantial change in micro structure of carbon aerogels was observed at carbonization temperature of 800 ºC which resulted in highest specific surface area and pore volume without any considerable change in average pore size. BET specific surface area and pore volume increased from 687 to 1775 m2 g-1 and 0.24 to 0.94 cm3 g-1 respectively whereas the pore size remained constant (around 2nm) after physical activation of the carbon aerogels using CO 2 as an activation agent.