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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Picco, L.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Microstructural Analysis of Ex-Service Neutron Irradiated Stainless Steel Nuclear Fuel Cladding by High-Speed AFM
- 2021Observation of stress corrosion cracking using real-time in situ high-speed atomic force microscopy and correlative techniquescitations
- 2019A study of dynamic nanoscale corrosion initiation events using HS-AFMcitations
- 2018Development of an adapted electrochemical noise technique for in-situ corrosion monitoring of spent nuclear fuel aqueous storage environments
- 2017Investigating corrosion using high-speed AFM
- 2017Ionic solutions of two-dimensional materials
- 2016Structural effects in UO$_2$ thin films irradiated with U ionscitations
- 2016Structural effects in UO2 thin films irradiated with U ionscitations
- 2015Characterisation of electrodeposited polycrystalline uranium dioxide thin films on nickel foil for industrial applicationscitations
- 2015Characterisation of electrodeposited polycrystalline uranium dioxide thin films on nickel foil for industrial applicationscitations
- 2014Growth and characterization of uranium-zirconium alloy thin films for nuclear industry applicationscitations
Places of action
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document
Development of an adapted electrochemical noise technique for in-situ corrosion monitoring of spent nuclear fuel aqueous storage environments
Abstract
Application of electrochemical noise (EN) monitoring within an industrial corrosion management system involves several prerequisites. An underpinning of electrochemical characteristics must be gained with respect to relevant corrosion mechanisms, and translated into a schematic and physical measurement system with high sensitivity and resilience to false positives. An adapted EN technique was developed using a non-symmetric electrochemical cell to confine localized corrosion to one functionalized working electrode, whilst considering the impact on interpretation. The materials studied included (i) a niobium stabilized stainless steel, used as a nuclear fuel clad material in the UK, and central to a nationally significant spent fuel management strategy and (ii) conventional stainless steels which form structural components of light water reactor (LWR) fuel assemblies. Observations were made in-situ of corrosion processes occurring through milli-to nanometer scale to correlate degradation mechanisms to EN signals. Time-resolved measurements were made simultaneously from multiple cells and analyzed in parallel to provide mechanism distinction, uncertainties and error capture, for example, data rejection during periods of heavy interference. This research presents the ability to embed, via a proportionate action level hierarchy, unambiguous, real time "early warning" information within highly complex operational corrosion management strategies.