693.932 PEOPLE
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Persson, Ingmar
Swedish University of Agricultural Sciences
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2020Solution chemistry in the surface region of aqueous solutionscitations
- 2019Chemical equilibria of aqueous ammonium-carboxylate systems in aqueous bulk, close to and at the water-air interfacecitations
- 2016Self-assembled SnO2 micro- and nanosphere-based gas sensor thick films from an alkoxide-derived high purity aqueous colloid precursorcitations
- 2015The structures of CyMe4-BTBP complexes of americium(III) and europium(III) in solvents used in solvent extraction, explaining their separation propertiescitations
- 2015The structures of CyMe4-BTBP complexes of americium(III) and europium(III) in solvents used in solvent extraction, explaining their separation propertiescitations
- 2014Speciation and structure of lead(II) in hyper-alkaline aqueous solutioncitations
- 2012Crystal Structures of [Hg10(dmso)16](ClO4)10 and [Hg2(H2O)2](ClO4)2citations
- 2010Structural Study of the N,N’-Dimethylpropyleneurea Solvated Lanthanoid(III) Ions in Solution and Solid State with an Analysis of the Ionic Radii of Lanthanoid(III) Ionscitations
- 2008Fenton-Induced Degradation of Polyethylene Glycol and Oak Cellulose. A Model Experiment in Comparison to Changes Observed in Conserved Waterlogged Woodcitations
- 2008Structure of solvated mercury(II) halides in liquid ammonia, triethyl phosphite and tri-n-butylphosphine solutioncitations
- 2007X-Ray Absorption Fine Structure Spectroscopic Studies of Octakis-(dimethylsulfoxide)lanthanoid(III) Complexes in Solution and in the Solid Iodidescitations
- 2006Crystal Structure of Lead(II) Acetylacetonate and the Structure of the Acetylacetone Solvated Lead(II) Ion in Solution Studied by Large Angle X-ray scatteringcitations
- 2004Structure of the Hydrated, Hydrolysed and Solvated Zirconium(IV) and Hafnium(IV) Ions in Water and Aprotic Oxygen Donor Solvents. A Crystallographic, EXAFS Spectroscopic and Large Angle X-ray Scattering Studycitations
- 2003Dimethyl Sulfoxide Solvates of the Aluminium(III), Gallium(III) and Indium(III) Ionscitations
- 2003A Structural Study of the Hydrated and the Dimethylsulfoxide, N,N’-Dimethyl-propyleneurea, Acetonitrile, Pyridine and N,N-Dimethylthioformamide Solvated Nickel(II) Ion Solution and Solid State
- 2003The discovery of the N,N-dimethylthioformamidium ion. A structural study of {(CH3)2NCHSH)}2[HfCl6] in solid state and solutioncitations
- 2001New Class of Oligonuclear Platinum-Thallium Compounds with a Direct Metal-Metal Bond. 5. Structure of Heterodimetallic Cyano Complexes in Aqueous Solution by EXAFS and Vibrational Spectroscopycitations
- 2001Crystal and Solution Structures of N,N-Dimethylthioformamide-Solvated Copper(I), Silver(I), and Gold(I) Ions Studied by X-ray Diffraction, X-ray Absorption, and Vibrational Spectroscopycitations
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article
A Structural Study of the Hydrated and the Dimethylsulfoxide, N,N’-Dimethyl-propyleneurea, Acetonitrile, Pyridine and N,N-Dimethylthioformamide Solvated Nickel(II) Ion Solution and Solid State
Abstract
The solvated nickel(II) ion is octahedral in aqueous (Ni-O bond distance 2.055(2) Å), dimethylsulfoxide (Ni-O 2.062(2)), acetonitrile (Ni-N 2.064(2)) and N,N-dimethylthioformamide (Ni-S 2.454(2)) solution. The permittivity of pyridine is too low to allow dissociation and tetrakis(pyridine)nickel(II) complexes with counter ions completing the octahedral configuration or mixed pyridine/water solvates are formed instead. The N,N′-dimethylpropyleneurea solvated nickel(II) ion is five-coordinated due to the bulkiness of the solvent molecule, with a mean Ni-O bond distance of 2.000(2) Å.