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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Van Aert, Sandra
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Investigation of the octahedral network structure in formamidinium lead bromide nanocrystals by low-dose scanning transmission electron microscopycitations
- 2024Single-Layered Imine-Linked Porphyrin-Based Two-Dimensional Covalent Organic Frameworks Targeting CO<sub>2</sub> Reductioncitations
- 2024Stabilizing Perovskite Pb(Mg<sub>0.33</sub>Nb<sub>0.67</sub>)O<sub>3</sub>-PbTiO<sub>3</sub> Thin Films by Fast Deposition and Tensile Mismatched Growth Templatecitations
- 2023Low-Dose 4D-STEM Tomography for Beam-Sensitive Nanocompositescitations
- 2023Fast generation of calculated ADF-EDX scattering cross-sections under channelling conditionscitations
- 2023Exploring the effects of graphene and temperature in reducing electron beam damagecitations
- 2022Element specific atom counting at the atomic scale by combining high angle annular dark field scanning transmission electron microscopy and energy dispersive X-ray spectroscopycitations
- 2022Atomic-scale detection of individual lead clusters confined in Linde Type A zeolitescitations
- 2021Interface Pattern Engineering in Core-Shell Upconverting Nanocrystals: Shedding Light on Critical Parameters and Consequences for the Photoluminescence Properties
- 2020Alloy CsCd x Pb 1- x Br 3 Perovskite Nanocrystals:The Role of Surface Passivation in Preserving Composition and Blue Emissioncitations
- 2020Alloy CsCd x Pb1-x Br3 Perovskite Nanocrystals: The Role of Surface Passivation in Preserving Composition and Blue Emissioncitations
- 2017One step toward a new generation of C-MOS compatible oxide PN junctionscitations
- 2016Long-range domain structure and symmetry engineering by interfacial oxygen octahedral coupling at heterostructure interfacecitations
- 2016Engineering properties by long range symmetry propagation initiated at perovskite heterostructure interface
- 2015Determination of the atomic width of an APB in ordered CoPt using quantified HAADF-STEMcitations
- 2014Lattice deformations in quasi-dynamic strain glass visualised and quantified by aberration corrected electron microscopycitations
- 2012Exit wave reconstruction from focal series of HRTEM images, single crystal XRD and total energy studies on Sb xWO 3+y (x ~ 0.11)citations
- 2009Effect of amorphous layers on the interpretation of restored exit wavescitations
Places of action
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article
Engineering properties by long range symmetry propagation initiated at perovskite heterostructure interface
Abstract
In epitaxial thin film systems, the crystal structure and its symmetry deviate from the bulk counterpart due to various mechanisms such as epitaxial strain and interfacial structural coupling, which induce an accompanying change in their properties. In perovskite materials, the crystal symmetry can be described by rotations of 6-fold coordinated transition metal oxygen octahedra, which are found to be altered at interfaces. Here, we unravel how the local oxygen octahedral coupling (OOC) at perovskite heterostructural interfaces initiates a different symmetry in epitaxial films and provide design rules to induce various symmetries in thin films by careful selecting appropriate combinations of substrate/buffer/film. Very interestingly we discovered that these combinations lead to symmetry changes throughout the full thickness of the film. Our results provide a deep insight into understanding the origin of induced crystal symmetry in a perovskite heterostructure and an intelligent route to achieve unique functional properties.