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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lee, Han-Seung
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Topics
Publications (9/9 displayed)
- 2024Bio-Based Corrosion Inhibition of Carbon Steel Using Ammi visnaga L. Essential Oil in Acidic Mediums: Experimental Analysis and Molecular Modelingcitations
- 2022Capacitive humidity sensing properties of freestanding bendable porous SiO2/Si thin filmscitations
- 2022Cupressus arizonica fruit essential oil: A novel green inhibitor for acid corrosion of carbon steel
- 2018Stress Corrosion Behavior of Ungrouted Pretensioned Concrete Beamscitations
- 2018Deposition of Coating to Protect Waste Water Reservoir in Acidic Solution by Arc Thermal Spray Process
- 2018Deposition of Coating to Protect Waste Water Reservoir in Acidic Solution by Arc Thermal Spray Processcitations
- 2017An effective and novel pore sealing agent to enhance the corrosion resistance performance of Al coating in artificial ocean water
- 2017Influence of Oil Palm Biomass Waste on Compressive Strength and Chloride Penetration of Mortar
- 2017Mechanical properties of different bamboo species
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article
Cupressus arizonica fruit essential oil: A novel green inhibitor for acid corrosion of carbon steel
Abstract
Natural-based corrosion inhibitors have gained great research interest thanks to their low cost and higher performance. The Cupressus arizonica fruit essential oil (CAFEO) has a higher extraction yield than leaves; however, it has less antibacterial and antifungal activities. The three main components in the CAFEO were α-pinene (51.07%), myrcene (17.92%), and limonene (9.66%). Essential oils with a higher percentage of α-pinene were found to have outstanding corrosion inhibition properties. Therefore, herein, the CAFEO was investigated as a green corrosion inhibitor for carbon steel (CS) in 1.0 mol/L HCl using electrochemical, i.e., potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS), and scanning electron microscope (SEM) techniques. The experimental results revealed that CAFEO successfully inhibited the carbon steel corrosion in 1.0 mol/L HCl solution. Results from PDP indicated that the inhibitor had a mixed-type effect with a predominance cathodic character. EIS data showed that the charge transfer resistance of the CS electrode increased from 20.9 Ω cm2 in blank solution to 294.5 Ω cm2 in HCl solution inhibited with 0.5 g/L of CAFEO at 298 K, leading to a significant decrease in the double layer capacitance values and an inhibition efficiency (η%) of 93%. The high temperatures showed a negative effect on the corrosion inhibition efficiency of the tested inhibitor. At 323 K, the η% of CAFEO decreased to 77%. Besides, SEM images showed that the inhibitor formed a protective barrier against acid attack, preventing carbon steel from corrosion. Theoretical calculations by Density Functional Theory (DFT) were performed to investigate the reactivity of the three main components of CAFEO.