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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lasgorceix, Marie
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (32/32 displayed)
- 20233D technology and antibacterial post-treatments: the process for the future manufacturing of bone substitutes?
- 2023Mg2+, Sr2+, Ag+, and Cu2+ co‐doped β‐tricalcium phosphate: Improved thermal stability and mechanical and biological propertiescitations
- 2023Fabrication of doped β-tricalcium phosphate bioceramics by Direct Ink Writing for bone repair applicationscitations
- 2023Synthesis and Direct Ink Writing of doped β-tricalcium phosphate bioceramics for bone repair applications
- 2023Shaping of complex ceramic parts by several additive manufacturing processes
- 2023Surface structuring of β-TCP and transition to α-TCP induced by femtosecond laser processingcitations
- 2023Macroporous biphasic calcium phosphate materials for bone substitute applications
- 2023Cold Sintering Process for developing hydroxyapatite ceramic and polymer composite
- 2023Cold Sintering Process for developing hydroxyapatite ceramic and polymer composite
- 20233D printing of doped β-tricalcium phosphate bioceramics using robocasting
- 2023Combination of indirect stereolithography and gel casting methods to shape ceramic dental crowns
- 2022Binder jetting process with ceramic powders ; Binder jetting process with ceramic powders: Influence of powder properties and printing parameterscitations
- 2022Shaping of complex ceramic parts using stereolithography and gel casting
- 2022Manufacturing methods of bioceramic scaffolds
- 2022Shaping of ceramics by hybrid binder jetting
- 2022Fabrication of doped β-tricalcium phosphate bioceramics by Direct Ink Writing for bone repair applicationscitations
- 2022Young Ceramists in the Spotlight
- 2022Shaping of ceramic by binder jetting
- 2022Fabrication of doped b-tricalcium phosphate bioceramics by robocasting for bone repair applications
- 2022Fabrication of doped b-tricalcium phosphate bioceramics by robocasting for bone repair applications
- 2022Post-infiltration to improve the density of binder jetting ceramic partscitations
- 2021Fabrication of higher thermal stability doped β-tricalcium phosphate bioceramics by robocasting
- 2021Influence of dopants on thermal stability and densification of β-tricalcium phosphate powderscitations
- 2021Development of calcium phosphate suspensions suitable for the stereolithography processcitations
- 2021Hybrid additive/subtractive manufacturing system to prepare dense and complicated ceramic parts
- 2020Fabrication of higher thermal stability doped β-tricalcium phosphate bioceramics by robocasting
- 2020Hybrid additive/subtractive manufacturing system to prepare dense and complex shape ceramic parts
- 2019Pre-osteoblast cell colonization of porous silicon substituted hydroxyapatite bioceramics: Influence of microporosity and macropore designcitations
- 2019Micropatterning of beta tricalcium phosphate bioceramic surfaces, by femtosecond laser, for bone marrow stem cells behavior assessmentcitations
- 2016Shaping by microstereolithography and sintering of macro–micro-porous silicon substituted hydroxyapatitecitations
- 2016Quantitative analysis of vascular colonisation and angio-conduction in porous silicon-substituted hydroxyapatite with various pore shapes in a chick chorioallantoic membrane (CAM) modelcitations
- 2014Shaping by microstereolithography and sintering of macro-micro-porous silicated hydroxyapatite ceramics and biological evaluation
Places of action
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document
Fabrication of doped b-tricalcium phosphate bioceramics by robocasting for bone repair applications
Abstract
b-tricalcium phosphate (b-TCP, b-Ca 3 (PO 4 ) 2 ) is one of the most attractive biomaterials for bone repair since it shows an excellent biological compatibility, osteoconductivity, and resorbability. It is already commercialized under granules or preforms for bone filling but there are still some issues for b-TCP porous scaffolds fabrication. Indeed, b-TCP cannot be used as scaffolds in large bone defects or in load-bearing areas due to its weak mechanical properties related to insufficient densification level. Indeed, the sintering temperature is limited because of the occurrence of a phase transition b to a-TCP at 1150°C with a large lattice expansion causing microcracks and reducing shrinkage during sintering. The thermal stability can be increased by the incorporation of dopants inside the b-TCP lattice. Indeed, such dopants like cations can replace the calcium inside the structure and stabilize the b phase reaching higher densities. Moreover, dopants can also improve biological properties of b-TCP as bone implant like the osteoconductivity or the antibacterial behaviour. In this work, doped b-TCP powders are synthetized by coprecipitation of Ca(NO 3 ) 2 and (NH 4 ) 2 HPO 4 solutions in presence of magnesium, strontium, silver and copper cations in order to prevent the phase transformation, increase the sintering temperature as well as the mechanical properties and bring an antibacterial behaviour. Rapid microwave sintering can then be successfully applied with a limited grain growth and compared with conventional sintering. Cytotoxicity and antibacterial evaluation are conducted to assess the potential of the doped b-TCP. Finally, 3D-printable suspensions are prepared from optimized doped powder to manufacture porous scaffolds by robocasting using water-based inks.