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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Reinsch, Stefan
Royal BAM Group (United Kingdom)
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2023Viscous Sintering of Acid Leached Glass Powderscitations
- 2023Viscous Sintering of Acid Leached Glass Powders
- 2023A new robot-assisted compositional screening method
- 2023Influence of Mo and B additions in intermetallic near-Fe3Al alloys on microstructure and mechanical propertiescitations
- 2022Microstructure evolution in Inconel 718 produced by powder bed fusion additive manufacturingcitations
- 2021Sample preparation for analytical scanning electron microscopy using initial notch sectioningcitations
- 2021Foaming Species and Trapping Mechanisms in Barium Silicate Glass Sealants
- 2021Foaming Species and Trapping Mechanisms in Barium Silicate Glass Sealantscitations
- 2021Vacuum crack growth in alkali silicate glassescitations
- 2020Water in Alkali Aluminosilicate Glassescitations
- 2020Crack Growth in Hydrous Soda-Lime Silicate Glasscitations
- 2020Automated analysis of slow crack growth in hydrous soda-lime silicate glassescitations
- 2019Structural investigation of hydrous phosphate glassescitations
- 2019The influence of H2O and SiO2 on the structure of silicoborate glassescitations
- 2019Increasing Exposed Metal Site Accessibility in a Co-MOF-74 Material With Induced Structure-Defectscitations
- 2019Hydrogen diffusivity in sodium aluminosilicate glassescitations
- 2019Surface crystallization and gas bubble formation during conventional heat treatment in Na2MnP2O7 glasscitations
- 2019Density, elastic constants and indentation hardness of hydrous soda-lime silica glassescitations
- 2019Analytical toolset to characterize polyurethanes after exposure to artificial weathering under systematically varied moisture conditionscitations
- 2018Structural relaxation mechanisms in hydrous sodium borosilicate glassescitations
- 2017Structural investigation of hydrous sodium borosilicate glassescitations
- 2017Ca- and Sr- tetrafluoroisophthalates: mechanochemical synthesis, characterization, and ab initio structure determinationcitations
- 2016Sintering and foaming of barium silicate glass powder compactscitations
- 2016Water, the other network modifier in borate glassescitations
- 2002Oberflächenkeimbildung von Silikatgläsern der Stöchiometrie des Cordierits und des Diopsids ; Surface nucleation of silicate glasses with cordierite and diopside stoichiometry
Places of action
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article
Viscous Sintering of Acid Leached Glass Powders
Abstract
The process of viscous flow sintering is a phenomenon that is closely linked to the surface properties of the glass particles. In this work, we studied the extreme case of acid-leaching of soda-lime-silicate glass beads of two different particle size distributions and its effects on non-isothermal viscous sintering of powder compacts. Depth profiling of the chemical composition after leaching revealed a near-surface layer depleted in alkali and alkaline earth ions, associated with concurrent hydration as mass loss was detected by thermogravimetry. Heating microscopy showed that acid treatment of glasses shifted the sinter curves to higher temperatures with increasing leaching time. Modelling of the shrinkage with the cluster model predicted a higher viscosity of the altered surface layer, while analysis of the time scales of mass transport of mobile species (Na+, Ca2+ and H2O) during isochronous sintering revealed that diffusion of Na+ can compensate for concentration gradients before sintering begins. Also, exchanged water species can diffuse out of the altered layer, but the depletion of Ca2+ in the altered surface layer persists during the sinter interval, resulting in a glass with higher viscosity, which causes sintering to slow down.