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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Meux, Eric
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Electroleaching and electrodeposition of silver in ethaline 1 : 2 and propeline 1 : 3: transport properties and electrode phenomena†
- 2023Propeline: a green alternative to Ethaline for electrochemical recovery of precious metals
- 2023Propeline : a new candidate for precious metal recovery 3rd International Meeting on Deep Eutectic Systems, Lisbonne, 19-22 juin 2023
- 2022Coupling electrochemical leaching and electrodeposition in ionic solvents for critical and precious metals recovery
- 2021Mass transport in Ionic Solvents during electrodeposition of gold and palladium
- 2021Greening effect of slag cement-based concrete: Environmental and ecotoxicological impactcitations
- 2021Electrochemical recovery of precious metals in Ionic Liquid mixtures or Deep Eutectic Solvents
- 2018Recovery of Metals from Secondary Raw Materials by Coupled Electroleaching and Electrodeposition in Aqueous or Ionic Liquid Mediacitations
- 2017Electrochemical recovery of platinum from spent proton exchange membrane fuel cells using ionic liquid melts
- 2016Direct recovery of cadmium and nickel from Ni-Cd spent batteries by electroassisted leaching and electrodeposition in a single-cell processcitations
- 2015Electroassisted leaching of black mass solids from Ni–Cd batteries for metal recovery: Investigation of transport and transfer phenomena coupled to reactionscitations
- 2015End-of-life nickel-cadmium accumulators: characterization of electrode materials and industrial Black Masscitations
- 2001Recherche d’un procédé hydrométallurgique de valorisation des poussières d’aciérie électriquecitations
Places of action
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conferencepaper
Coupling electrochemical leaching and electrodeposition in ionic solvents for critical and precious metals recovery
Abstract
The development of technologies that allow us to recycle or reuse waste electrical and electronic equipment (WEEE) is paramount in order to create an environmentally sustainable economy. It is also noteworthy that the percentage of some metals in WEEE is larger than in their natural sources, thus generating economic interest in their recycling [1]. Notably, the concentration of precious metals (e.g. Au, Ag, Pd, Pt) in High Tech end-of-life products like smartphones or tablets can be ten to twenty-five times higher than in ores. Generally, precious metals sludges produced by pyrometallurgical primary treatments are treated using multi-step complex hydrometallurgical processes, that have some important limitations for workers or installation safety and remain far from sustainable development considerations. Besides, these pyrometallurgical processes dilute many “minor”, but critical metals (Sn, Sb, Ta…) in the multimetallic outgoing fraction, so that they cannot be recovered in a viable way.In this context, the promising properties of ionic solvents might be an opportunity to design new metal recovery processes being more respectful of Green Chemistry principles with less wastewater generation, less reactants used and less hazards associated. We will present the potentialities of coupling electrochemical leaching and deposition (EL-ECD) in a single cell using ionic solvents for the recovery of precious metals (Au, Pt, Pd, Ag) from rich-metallic waste issued from WEEE primary treatment. The influence of anionic part of various ionic solvents on metals electrochemical behavior was studied by electrochemical techniques. Metal speciation and kinetics parameters associated to electrochemical reactions were determined in most promising electrolytes, by spectroscopic and electrochemical transient/stationary techniques respectively. The performances of the process, namely leaching and electrodeposition efficiencies, were established in ambient atmosphere. Faradaic yields, recovery rates and selectivity for mono and ...