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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tran, Thi Tuyet Mai
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Topics
Publications (11/11 displayed)
- 2023Erosion-corrosion of copper in cooling water systems at 60°C using an impinging liquid jet and Electrochemical Quartz Crystal Microbalance
- 2021Corrosion and hydrogen permeation in H2S environments with O2 contamination – Part 3: the impact of acetate-buffered test solution chemistrycitations
- 2020Impact of oxygen contamination on the electrochemical impedance spectroscopy of iron corrosion in H2S solutionscitations
- 2019Corrosion and hydrogen permeation of low alloy steel in H2S-containing environments : the effect of test buffer solution chemistry
- 2019EIS study of iron and steel corrosion in aqueous solutions at various concentrations of dissolved H2S : impact of oxygen contamination.
- 2019Corrosion and Hydrogen Permeation in H2S Environments with O2 Contamination, Part 2: Impact of H2S Partial Pressurecitations
- 2018Corrosion of Pure iron and Hydrogen Permeation in the Presence of H 2 S with O 2 contamination
- 2018Electrochemical study of oxygen impact on corrosion and hydrogen permeation of Armco iron in the presence of H 2 S
- 2017Impact of Oxygen on Corrosion and Hydrogen Permeation of Pure iron in the Presence of H2S
- 2016Facile and Green Synthesis of Polyoxometalate-Reduced Graphene Oxide Nanocomposite
- 2012Anomalous Dissolution of Copper in Al-Cu alloys
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document
Anomalous Dissolution of Copper in Al-Cu alloys
Abstract
During galvanic coupling between copper and aluminium, copper can undergo anomalous dissolution and replating onto the surface of aluminium. This observation has often been made on 2024-T3 alloys at a micrometric scale, at the interface between the aluminium-rich matrix and the intermetallic particles, as well as at a more macroscopic scale, in the vicinity of the interface between a 2024 sheet and a rivet with similar composition. The aim of this work is to show that anomalous copper dissolution has to be correlated with the presence of a confined medium, rather than with galvanic coupling. A confined medium was simulated using a thin-layer electrochemical cell and copper replating at the mouth of the crevice was followed using EDS analysis. A mechanism is suggested involving local acidification in the crevice, due to Al dissolution. Furthermore pH variations between the inner acidic zone and the more alkaline zone at the mouth of the crevice have also to be taken into account.