| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Damsgaard, Christian Danvad
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (28/28 displayed)
- 2024Using CoCu2Ga/SiO2 to identify stability-issues in ethanol-selective Co-Cu alloyed catalysts in carbon monoxide hydrogenationcitations
- 2024Using CoCu 2 Ga/SiO 2 to identify stability-issues in ethanol-selective Co-Cu alloyed catalysts in carbon monoxide hydrogenationcitations
- 2024Using CoCu$_2$Ga/SiO$_2$ to identify stability-issues in ethanol-selective Co-Cu alloyed catalysts in carbon monoxide hydrogenation
- 2024Stable mass-selected AuTiOx nanoparticles for CO oxidationcitations
- 2024Stable mass-selected AuTiO x nanoparticles for CO oxidationcitations
- 2023Ni 5-x Ga 3+x Catalyst for Selective CO 2 Hydrogenation to MeOH :Investigating the Activity at Ambient Pressure and Low Temperature with Microreactors
- 2023Ni5-xGa3+x Catalyst for Selective CO2 Hydrogenation to MeOH
- 2022Reversible Atomization and Nano-Clustering of Pt as a Strategy for Designing Ultra-Low-Metal-Loading Catalystscitations
- 2021Characterization of oxide-supported Cu by infrared measurements on adsorbed COcitations
- 2020Reduction and carburization of iron oxides for Fischer–Tropsch synthesiscitations
- 2019Evolution of intermetallic GaPd2/SiO2 catalyst and optimization for methanol synthesis at ambient pressurecitations
- 2018Scalable Synthesis of Carbon-Supported Platinum–Lanthanide and −Rare-Earth Alloys for Oxygen Reductioncitations
- 2016Influence of gas atmospheres and ceria on the stability of nanoporous gold studied by environmental electron microscopy and in situ ptychographycitations
- 2015Intermetallic GaPd2 Nanoparticles on SiO2 for Low-Pressure CO2 Hydrogenation to Methanolcitations
- 2015Intermetallic GaPd 2 Nanoparticles on SiO 2 for Low-Pressure CO 2 Hydrogenation to Methanol:Catalytic Performance and In Situ Characterizationcitations
- 2014In situ ETEM synthesis of NiGa alloy nanoparticles from nitrate salt solutioncitations
- 2014In situ observation of Cu-Ni alloy nanoparticle formation by X-ray diffraction, X-ray absorption spectroscopy, and transmission electron microscopy: Influence of Cu/Ni ratiocitations
- 2014Intermetallic compounds of Ni and Ga as catalysts for the synthesis of methanolcitations
- 2014Intermetallic compounds of Ni and Ga as catalysts for the synthesis of methanolcitations
- 2014Electron microscopy study of the deactivation of nickel based catalysts for bio oil hydrodeoxygenation
- 2013Optical coupling in the ETEM
- 2012Origin of low temperature deactivation of Ni5Ga3 nanoparticles as catalyst for methanol synthesis
- 2011In situ environmental transmission electron microscope investigation of NiGa nanoparticle synthesis
- 2009Interfacial, electrical, and spin-injection properties of epitaxial Co2MnGa grown on GaAs(100)citations
- 2008Hybrid Spintronic Structures With Magnetic Oxides and Heusler Alloyscitations
- 2006Spin injection from epitaxial Heusler alloy thin films into InGaAs/GaAs quantum wells
- 2005Fe-contacts on InAs(100) and InP(100) characterised by conversion electron Mössbauer spectroscopycitations
- 2005Spin injection between epitaxial Co2.4Mn1.6Ga and an InGaAs quantum wellcitations
Places of action
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document
Ni5-xGa3+x Catalyst for Selective CO2 Hydrogenation to MeOH
Abstract
Methanol obtained from the direct hydrogenation of CO<sub>2</sub> at low pressures and temperatures can be used as a fuel/chemical feedstock and, if paired with renewable energy sources, could strongly contribute to reach a more sustainable society.<br/><br/>We have studied the catalytic performance of the intermetallic compound Ni<sub>5- x</sub>Ga<sub>3+x</sub> for methanol production. The catalyst shows outstanding activity and selectivity at low temperatures, outperforming the conventional Cu/ZnO. At higher T, the selectivity promptly shifts towards the production of methane and CO, leading to surface poisoning. Nevertheless, the experiments demonstrate the possibility of full regeneration of the catalyst by hydrogen reduction. Lastly, high stability over time under reaction conditions makes it an interesting candidate for scale-up and future industrial application. <br/><br/>A variety of techniques are used to characterize the surface before and after reaction, including XPS, HR-SEM/STEM, XRD, etc., along with close collaboration with computational theoreticians for DFT calculations. All the experiments are performed in state-of-the-art equipment: microreactors of 256 nL are used for catalytic testing. The inlet flow rate is in the order of magnitude of nanomoles/min, making it possible for all the gases to enter directly the QMS, leading to extremely high product detection sensitivity. This, together with an almost immediate temperature control, makes our system ideal for further fundamental studies about CO<sub>2</sub> hydrogenation.