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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Shahid, Sammia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Carbon dots and nitrogen-doped carbon dots-metal oxide nanocomposites
- 2023Synthesis of Mn-Doped ZnO Nanoparticles and Their Application in the Transesterification of Castor Oil
- 2023A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrolecitations
- 2022Green synthesis of a MnO-GO-Ag nanocomposite using leaf extract of Fagonia arabica and its antioxidant and anti-inflammatory performancecitations
- 2022Biogenic plant mediated synthesis of monometallic zinc and bimetallic Copper/Zinc nanoparticles and their dye adsorption and antioxidant studiescitations
- 2022Controlled growth of nanocomposite thin layer based on Zn-Doped MgO nanoparticles through Sol-Gel technique for biosensor applicationscitations
- 2021Synthesis of novel ternary hybrid g-C3N4@Ag-ZnO nanocomposite with Z-scheme enhanced solar light-driven methylene blue degradation and antibacterial activitiescitations
- 2021Fabricated novel g-C3N4/Mn doped ZnO nanocomposite as highly active photocatalyst for the disinfection of pathogens and degradation of the organic pollutants from wastewater under sunlight radiationscitations
- 2021Designing of highly active g-C3N4/Ni-ZnO photocatalyst nanocomposite for the disinfection and degradation of the organic dye under sunlight radiationscitations
- 2021Designing of highly active g-C3N4/Sn doped ZnO heterostructure as a photocatalyst for the disinfection and degradation of the organic pollutants under visible light irradiationcitations
- 2020Green Synthesis of MnO Nanoparticles using Abutilon indicum Leaf Extract for Biological, Photocatalytic, and Adsorption Activitiescitations
- 2020Enhanced photocatalytic activity by the fabricated TiO2/Graphene oxide nanocomposites against ciprofloxacin and methylene blue dye
- 2020Highly efficient g-C3N4/Cr-ZnO nanocomposites with superior photocatalytic and antibacterial activitycitations
- 2019Synthesis of TiO2/Graphene oxide nanocomposites for their enhanced photocatalytic activity against methylene blue dye and ciprofloxacincitations
Places of action
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article
Synthesis of Mn-Doped ZnO Nanoparticles and Their Application in the Transesterification of Castor Oil
Abstract
Alarming environmental changes and the threat of natural fuel resource extinction are concerning issues in human development. This has increased scientists’ efforts to phase out traditional energy resources and move on to environmentally friendly biofuels. In this study, non-edible castor oil was transesterified with methanol using a manganese-doped zinc oxide (Mn-doped ZnO) nanocatalyst. A heterogeneous nanocatalyst was prepared by means of the the sonochemical method. X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM) were used to characterize these nanocatalysts. The transesterification reaction was studied under different temperature conditions, different ratios of methyl alcohol to castor oil, and different amounts of the catalyst to identify optimum conditions in which the maximum yield of biodiesel was produced. The maximum biodiesel yield (90.3%) was observed at 55 °C with an oil-to-methanol ratio of 1:12, and with 1.2 g of nanocatalyst. The first-order kinetic model was found to be the most suitable. Several thermodynamic parameters were also determined, such as activation energy, enthalpy, and entropy. We found that this transesterification was an endergonic and entropy-driven reaction. The results showed that the Mn-doped ZnO nanocatalyst could be a suitable catalyst for the heterogeneous catalytic transesterification process, which is essential for biodiesel production.