Materials Map

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (5/5 displayed)

  • 2023Engineering the nano and micro structures of sputtered HfZrO2 thin filmscitations
  • 2022Fabrication process for sub-8 nm HfZrO2-based ferroelectric tunnel junctions with enhanced propertiescitations
  • 2022Ferroelectricity Improvement in Ultra-Thin Hf0.5Zr0.5O2 Capacitors by the Insertion of a Ti Interfacial Layer9citations
  • 2022How to play on the fabrication process of HfZrO2 ferroelectric thin film to enhance its physical propertiescitations
  • 2021Effect of bottom electrodes on HZO thin film propertiescitations

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Chart of shared publication
Baboux, Nicolas
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Deleruyelle, Damien
5 / 26 shared
Barhoumi, Rabei
5 / 22 shared
Romeo, Pedro Rojo
5 / 18 shared
Segantini, Greta
5 / 23 shared
Bouaziz, Jordan
2 / 18 shared
Manchon, Benoît
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Vilquin, Bertrand
5 / 68 shared
Nirantar, Shruti
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Jeannot, Simon
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Manchon, Benoit
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Bugnet, Matthieu
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Sriram, Sharath
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Co-Authors (by relevance)

  • Baboux, Nicolas
  • Deleruyelle, Damien
  • Barhoumi, Rabei
  • Romeo, Pedro Rojo
  • Segantini, Greta
  • Bouaziz, Jordan
  • Manchon, Benoît
  • Vilquin, Bertrand
  • Nirantar, Shruti
  • Jeannot, Simon
  • Manchon, Benoit
  • Bugnet, Matthieu
  • Sriram, Sharath
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document

Engineering the nano and micro structures of sputtered HfZrO2 thin films

  • Baboux, Nicolas
  • Deleruyelle, Damien
  • Barhoumi, Rabei
  • Romeo, Pedro Rojo
  • Infante, Ingrid Cañero
  • Segantini, Greta
  • Bouaziz, Jordan
  • Manchon, Benoît
  • Vilquin, Bertrand
Abstract

We focus on (Hf,Zr)O2 thin films deposition for the capacitor of FRAM in the 1T-1C. (Hf,Zr)O2 thin films are studied to either fully understand the stabilization of the ferroelectric phase or to fit with industrial requirements. Changing the pressure in our sputtering chamber during the room temperature deposition lead to the deposition of crystalline or amorphous films. After a Rapid Thermal Annealing, only the amorphous films crystallize in the ferro-phase [1]. Samples are stacks of Si/TiN/Hf0.5Zr0.5O/TiN/Pt. The samples are called NM, and M: NM and M refers to two different architectures, respectively non-mesa and mesa structures [2]. The set-up for electrical measurements have been described in reference [3]. We report the fabrication of two samples deposited by magnetron sputtering with excellent performances, quite similar to samples deposited by ALD. Pr values are among the highest for samples deposited by sputtering. Although the N-sample and NM-samples show very close Pr values, the two samples show completely different electrical behaviors. During cycling, the increase of Pr value for the NM-sample is more than an order of magnitude higher than the M-sample. It is accompanied by a decrease of the endurance which is two order of magnitude higher for the NM-sample than for the M-sample. The origins of the different electrical behaviors come from the micro-crystalline structures of the two samples, according to GIXRD results. The crystallization takes place during the annealing step. It induces different stress states which lead to two different micro-crystalline patterning. The M-sample shows no monoclinic peak, whereas the NM-sample shows many monoclinic orientations. It can explain the huge reduction of the wake-up effect.[1] J. Bouaziz et al. JVST B 37, 021203 (2019).[2] J. Bouaziz et al. ACS Appl. Electron. Mater. 1, 1740 (2019).[3] J. Bouaziz et al. APL Mater. 7, 081109 (2019).

Topics
  • Deposition
  • impedance spectroscopy
  • amorphous
  • phase
  • thin film
  • annealing
  • tin
  • crystallization