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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Robbiola, Luc
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Fire gilding investigation on early medieval copper-based jewellery by focused ion beam (FIB) on FEG-SEMcitations
- 2022Galvanic corrosion over World War II aircraft wrecks
- 2022Galvanic corrosion over World War II aircraft wrecks
- 2022Analysis of Chromate-based Primers for Protection of Aluminium Alloys on Historical Aircraftcitations
- 2020Technological characterisation of early Medieval gilded copper hollow pendants (gombiky), from Mikulčice (Moravia) and Prague Castle (Bohemia)citations
- 2019Early medieval "gombiky" from Mikulčice: archaeological context, function, occurence, typology, construction, and characterization of materials and manufacturing processes ; Les "gombiky" du haut Moyen Âge de Mikulčice : contexte archéologique, fonction, occurrence, typologie, construction et caractérisation des matériaux et des processus de fabrication.
- 2019Evaluation of the protectiveness of an organosilane coating on patinated Cu-Si-Mn bronze for contemporary artcitations
- 2017Microstructure and thermal analysis of Cu-Cu2O eutectic – Can we mimic archeological remains?
- 2016Efficienza inibitrice di basi di schiff come inibitori di corrosione del bronzo
- 2005Corrosion and protection of high leaded tin bronze covered with patina in NaHCO3 + Na2SO4 solution simulating acid rain in urban environment
Places of action
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article
Efficienza inibitrice di basi di schiff come inibitori di corrosione del bronzo
Abstract
As part of an M-ERA.NET project called B-IMPACT some polidentate Schiff bases were synthesized and tested as corrosion inhibitors of bronze. The tests consisted of exposures of bronze specimens to a concentrated artificial acid rain solution, containing or not containing the studied substances added under saturation conditions (< 10(3) M). Their inhibiting effect was evaluated during 20 day immersions by means of non-destructive electrochemical tests (Electrochemical Impedance Spectroscopy) and by finally recording the polarization curves. Observations by a scanning electron microscope coupled with Energy Dispersive X-ray Spectroscopy allowed comparing the morphology of corrosion attack in the absence and presence of inhibitors. The best inhibiting properties were achieved in the presence of 2-(salicylideneimino)thiophenol (SITP). The addition of phosphate ions to SITP induced the formation of a surface film particularly resistant against localized corrosion phenomena. Raman and XPS spectroscopy were applied in order to investigate the inhibition mechanism of sire without and with the presence of phosphate ions.