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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ameruddin, Amira S.
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Topics
Publications (8/8 displayed)
- 2022Tuning the crystal structure and optical properties of selective area grown InGaAs nanowirescitations
- 2021Tuning the crystal structure and optical properties of selective area grown InGaAs nanowires
- 2020Nanocomposite Assisted Green Synthesis of Polyvinylpyrrolidone-Silver Nanocomposite Using Pandanus atrocarpus Extract for Antiurolithiatic Activity
- 2017Effect on Different Amount of TiO2 P25 powder for Dye-Sensitized Solar Cell application
- 2016Bandgap Energy of Wurtzite InAs Nanowirescitations
- 2015InxGa1-xAs nanowires with uniform composition, pure wurtzite crystal phase and taper-free morphologycitations
- 2015InxGa1-xAs nanowires with uniform composition, pure wurtzite crystal phase and taper-free morphologycitations
- 2014Influence of InxGa1-xAs Underlying Layer on the Structural of the In0.5Ga0.5As Quantum Dots Grown by MOCVD
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article
Tuning the crystal structure and optical properties of selective area grown InGaAs nanowires
Abstract
Catalyst-free InGaAs nanowires grown by selective area epitaxy are promising building blocks for future optoelectronic devices in the infrared spectral region. Despite progress, the role of pattern geometry and growth parameters on the composition, microstructure, and optical properties of InGaAs nanowires is still unresolved. Here, we present an optimised growth parameter window to achieve highly uniform In1−xGaxAs nanowire arrays on GaAs (111)B substrate over an extensive range of Ga concentrations, from 0.1 to 0.91, by selective-area metal-organic vapor-phase epitaxy. We observe that the Ga content always increases with decreasing In/(Ga+In) precursor ratio and group V flow rate and increasing growth temperature. The increase in Ga content is supported by a blue shift in the photoluminescence peak emission. The geometry of the nanowire arrays also plays an important role in the resulting composition. Notably, increasing the nanowire pitch size from 0.6 to 2 µm in a patterned array shifts the photoluminescence peak emission by up to 120 meV. Irrespective of these growth and geometry parameters, the Ga content determines the crystal structure, resulting in a predominantly wurtzite structure for xGa ≤ 0.3 and a predominantly zinc blende phase for xGa ≥ 0.65. These insights on the factors controlling the composition of InGaAs nanowires grown by a scalable catalyst-free approach provide directions for engineering nanowires as functional components of future optoelectronic devices.