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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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West, A. R.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2023Redox-active oxygen in oxides: emergent applications, including field-induced resistive switching, flash luminescence, p–n junctions and high capacity battery cathodes
- 2023Impedance and dielectric spectroscopy of functional materials: a critical evaluation of the two techniques
- 2019Synthesis, structure and dielectric properties of a new family of phases, ABC3O11 : A = La, Pr, Nd, Sm, Gd; B = Zr, Hf; C = Ta, Nb
- 2018Electrical properties of yttria-stabilized zirconia, YSZ single crystal: Local AC and long range DC conductioncitations
- 2016Spinel–rock salt transformation in LiCoMnO4−δcitations
- 2016Synthesis, structure and electrical properties of N-doped Li3VO4citations
- 2001Characterization of lanthanum-doped barium titanate ceramics using impedance spectroscopy
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article
Characterization of lanthanum-doped barium titanate ceramics using impedance spectroscopy
Abstract
The electrical properties of two single-phase, lanthanum-doped BaTiO3 compositions, x = 0.03 and x = 0.20, in Ba1-xLaxTi1-x/4O3 were investigated by impedance spectroscopy after heat treatment in oxygen, argon, and air at 1350 degreesC. Samples heated in oxygen were electrically insulating, whereas those heated in argon lost oxygen and were semiconducting at room temperature, irrespective of x, Samples heated in air showed intermediate electrical properties and also were electrically inhomogeneous; the two compositions showed different electrical behaviors, and a model for each, based on oxygen nonstoichiometry within the ceramics, is proposed, Oxygen deficiency in samples sintered in air was avoided by heating at 1200 degreesC, instead of 1350 degreesC. Alternatively, oxygen lost from ceramics heated in air at 1350 degreesC was regained by postannealing in oxygen at 1350 degreesC.