693.932 PEOPLE
| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Thurn-Albrecht, Thomas
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (41/41 displayed)
- 2024Poly-3-hydroxybutyrate, a Crystal-Mobile Biodegradable Polyester
- 2024Controlling crystal orientation in films of conjugated polymers by tuning the surface energy
- 2023On thermodynamics and kinetics of interface-induced crystallization in polymers
- 2023How entanglements determine the morphology of semicrystalline polymers
- 2022Bulk enthalpy of melting of Poly (l-lactic acid) (PLLA) determined by fast scanning chip calorimetry
- 2022Bulk Enthalpy of Melting of Poly (l-lactic acid) (PLLA) Determined by Fast Scanning Chip Calorimetry
- 2022Competition between crystal growth and intracrystalline chain diffusion determines the lamellar thickness in semicrystalline polymerscitations
- 2022Competition between crystal growth and intracrystalline chain diffusion determines the lamellar thickness in semicrystalline polymers
- 2021Digitally Tuned Multidirectional All-Polyethylene Composites via Controlled 1D Nanostructure Formation during Extrusion-Based 3D Printingcitations
- 2020Influence of ω-Bromo Substitution on Structure and Optoelectronic Properties of Homopolymers and Gradient Copolymers of 3-Hexylthiophenecitations
- 2020Structure–Property Relationships of Microphase-Separated Metallosupramolecular Polymerscitations
- 2019Intracrystalline Dynamics in Oligomer‐Diluted Poly(Ethylene Oxide)citations
- 2018Modular Synthesis and Structure Analysis of P3HT-b-PPBI Donor–Acceptor Diblock Copolymerscitations
- 2018The Underestimated Effect of Intracrystalline Chain Dynamics on the Morphology and Stability of Semicrystalline Polymerscitations
- 2017Manipulating Semicrystalline Polymers in Confinementcitations
- 2016Influence of Fullerene Grafting Density on Structure, Dynamics, and Charge Transport in P3HT-<i>b</i>-PPC<sub>61</sub>BM Block Copolymerscitations
- 2016Thermally stable and efficient polymer solar cells based on a novel donor-acceptor copolymercitations
- 2016Crystallization of Poly(ethylene oxide) with a Well-Defined Point Defect in the Middle of the Polymer Chaincitations
- 2014Detection of Surface-Immobilized Components and Their Role in Viscoelastic Reinforcement of Rubber–Silica Nanocompositescitations
- 2014Studying Twin Samples Provides Evidence for a Unique Structure-Determining Parameter in Simplifed Industrial Nanocompositescitations
- 2014Donor–acceptor block copolymers carrying pendant PC<sub>71</sub>BM fullerenes with an ordered nanoscale morphologycitations
- 2014Nanostructure and Rheology of Hydrogen-Bonding Telechelic Polymers in the Melt: From Micellar Liquids and Solids to Supramolecular Gelscitations
- 2014Studying Twin Samples Provides Evidence for a Unique Structure-Determining Parameter in Simplifed Industrial Nanocompositescitations
- 2013Phase Separation in the Melt and Confined Crystallization as the Key to Well-Ordered Microphase Separated Donor–Acceptor Block Copolymerscitations
- 2013Crystallization of Supramolecular Pseudoblock Copolymerscitations
- 2012Investigation of the different stable states of the cantilever oscillation in an atomic force microscopecitations
- 2012Mechanical Properties and Cross-Link Density of Styrene–Butadiene Model Composites Containing Fillers with Bimodal Particle Size Distributioncitations
- 2012Thermotropic Behavior, Packing, and Thin Film Structure of an Electron Accepting Side-Chain Polymercitations
- 2011Poly(ε-caprolactone)-poly(isobutylene): A crystallizing, hydrogen-bonded pseudo-block copolymercitations
- 2011Crystallization and Melting of Poly(ethylene oxide) in Blends and Diblock Copolymers with Poly(methyl acrylate)citations
- 2010Morphology development and compatibilization effect in nanoclay filled rubber blendscitations
- 2010Fabrication and characterization of a biomimetic composite scaffold for bone defect repaircitations
- 2010High Crystallinity and Nature of Crystal−Crystal Phase Transformations in Regioregular Poly(3-hexylthiophene)citations
- 2010Tuning and Switching the Hypersonic Phononic Properties of Elastic Impedance Contrast Nanocompositescitations
- 2010Fiber - and Tube - Formation by Melt Infiltration of Block Copolymers into Al<sub>2</sub> O<sub>3</sub> -Porescitations
- 2009Quantitative Analysis of Scanning Force Microscopy Data Using Harmonic Modelscitations
- 2004Semicrystalline morphology in thin films of poly(3-hexylthiophene)
- 2001On exfoliation of montmorillonite in epoxycitations
- 2001Electrohydrodynamic instabilities in polymer films
- 2000X-ray scattering study and molecular simulation of glass forming liquids: Propylene carbonate and salolcitations
- 2000Electrically induced structure formation and pattern transfer citations
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article
Semicrystalline morphology in thin films of poly(3-hexylthiophene)
Abstract
The thermodynamic phase behavior and the morphology in thin films of poly(3-hexylthiophene) (P3HT) has been studied using calorimetry, X-ray scattering, and scanning force microscopy (AFM). Around 225 °C a phase transition from the crystalline state to a layered, liquid crystalline structure occurs in regioregular P3HT, while the regiorandom counterpart material is disordered at all temperatures and displays a glass transition temperature T g ≈−3 °C. Regioregular P3HT is semicrystalline and forms needle or plate like crystallites which in solution cast thin films are oriented with respect to the substrate. Films produced by spin coating display a non-equilibrium structure with reduced order and orientation. Annealing of these films in the liquid crystalline state leads to the formation of a morphology similar to the one observed in solution cast films.