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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Erik Weinell, Claus
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (33/33 displayed)
- 2024Protective Mechanisms of Siloxane-Modified Epoxy Novolac Coatings at High-Pressure, High-Temperature Conditions
- 2024Advancing Coating Science: Non-Destructive Methods for Coating Degradation Evaluation and Breakdown Mechanism Investigation
- 2023Incorporation of unmodified technical Kraft lignin particles in anticorrosive epoxy novolac coatings
- 2023Trust, but verify!
- 2023Chemically-resistant epoxy novolac coatings: Effects of size-fractionated technical Kraft lignin particles as a structure-reinforcing componentcitations
- 2022Marine biofouling resistance rating using image analysiscitations
- 2022Detection and quantification of premature crack formation in curing epoxy coatingscitations
- 2022Encapsulated Inhibitive Pigment for Smart Anti-corrosive Epoxy Coatings
- 2022A Tunable Hyperspectral Imager for Detection and Quantification of Marine Biofouling on Coated Surfacescitations
- 2022Coating degradation and rust creep assessment - A comparison between a destructive method according to ISO 12944 and selected non-destructive methods
- 2022Parallel measurements and engineering simulations of conversion, shear modulus, and internal stress during ambient curing of a two-component epoxy coatingcitations
- 2022Self-stratification studies in waterborne epoxy-silicone systemscitations
- 2022Non-destructive Evaluation of Coating Degradation and Rust Creep
- 2021Methanol degradation mechanisms and permeability phenomena in novolac epoxy and polyurethane coatingscitations
- 2021The influence of CO2 at HPHT conditions on properties and failures of an amine-cured epoxy novolac coatingcitations
- 2021Simultaneous tracking of hardness, reactant conversion, solids concentration, and glass transition temperature in thermoset polyurethane coatingscitations
- 2021A Tannin-based Inhibitive Pigment for a Sustainable Anti-corrosive Epoxy Coating Formulation
- 2021Degradation pathways of amine-cured epoxy novolac and bisphenol F resins under conditions of high pressures and high temperatures
- 2021Effects of Biochar Nanoparticles on Anticorrosive Performance of Zinc-rich Epoxy Coatingscitations
- 2021Rust creep assessment - A comparison between a destructive method according to ISO 12944 and selected non-destructive methodscitations
- 2021Simultaneous tracking of hardness, reactant conversion, solids concentration, and glass transition temperature in thermoset polyurethane coatingscitations
- 2021The evolution of coating properties and internal stress during ambient curing of a two-component epoxy coating
- 2019Corrosion Protection of Epoxy Coating with Calcium Phosphate Encapsulated by Mesoporous Silica Nanoparticles
- 2019Exposure of hydrocarbon intumescent coatings to the UL1709 heating curve and furnace rheology: Effects of zinc borate on char propertiescitations
- 2019Measurements of methanol permeation rates across thermoset organic coatings
- 2009Advancements in high performance zinc epoxy coatings
- 2008Non-destructive determination of rust creep
- 2007Advancement in zinc rich epoxy primers for corrosion protection
- 2007Adhesion between coating layers based on epoxy and siliconecitations
- 2006Dissolution rate measurements of sea water soluble pigments for antifouling paintscitations
- 2006Anti-fouling silicone elastomers for offshore structures
- 2005Reaction rate estimation of controlled-release antifouling paint binders: Rosin-based systemscitations
- 2005Reaction rate estimation of controlled-release antifouling paint binders: Rosin-based systemscitations
Places of action
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document
Encapsulated Inhibitive Pigment for Smart Anti-corrosive Epoxy Coatings
Abstract
Applying organic coatings is the most common way to protect metal structures from corrosion failures. An anti-corrosive coating offers an effective physical barrier, impeding the diffusion of corrosive species to the metal substrate. To enhance the coatings’ anti-corrosive properties, the addition of pigments that inhibit the corrosion process is required if the barrier effect is disrupted.<br/><br/>In a conventional coating, the water uptake and the prolonged exposure to wet conditions can wash away part of the inhibitive pigment. This spontaneous release regardless of whether or not corrosion is likely to occur, can lead to a fast depletion of the coating from the inhibitive pigment and also sacrifice the barrier properties of the coating film. Thus, a higher pigment concentration is needed for sufficient long-term protection. Smart coatings with encapsulated inhibitive pigment, on the other hand, are able to respond to external triggering like changes in the pH and release the inhibitive species from the functional nanoparticles. The controlled release of the inhibitive ions prevents spontaneous material losses and enhances the durability of the coatings.<br/><br/>In the present work, calcium phosphate was encapsulated into mesoporous silica nanoparticles (MSN). The effect of pH on the structure and morphology of the MSN and the release of calcium phosphate from the MSN was investigated. Epoxy coatings with encapsulated (3 wt.%) and non-encapsulated (3 wt.% and 5 wt.%) calcium phosphate were formulated and their anti-corrosive performance was evaluated by Open Circuit Potential (OCP) and Electrochemical Impedance Spectroscopy (EIS) techniques. Results showed that encapsulation of the calcium phosphate as inhibitive pigment in the epoxy coating can enhance the anti-corrosive performance by preventing spontaneous pigment dissolution and controlling the pigment’s release from the coating.